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广州某退役稀土厂场地放射性及重金属污染特征

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以广州某退役稀土厂场地为例,开展放射性和重金属污染特征研究,为后期治理提供基础数据。用高纯锗γ能谱仪和ICP-MS分别测量厂区土壤样品中天然放射性核素和重金属含量,同时在采样点测量γ辐射空气吸收剂量率。结果表明,厂区γ辐射空气吸收剂量率变化范围为113~4004 nGy/h,废渣堆放区明显偏高;土壤样品的238U、232Th、226Ra和40K含量分别是80。8~1990。2、78。4~14372。4、68。2~6935。0和625。4~2698。4 Bq/kg;测量的8种重金属中,As超土壤修复标准较严重,最高达263。83 mg/kg,Zn和Pb也存在一定程度的超标。厂区土壤和废渣的pH值均符合污染场地土壤修复标准要求,而土壤中放射性和重金属复合污染较严重,在开发再利用前要进行详细场地调查和土壤修复工作。
Characteristics of Radioactivity and Heavy Metal Pollution at a Rare Earth Factory Site in Guangzhou
Taking a retired rare earth plant site in Guangzhou as an example,a study on the characteristics of radioactive and heavy metal pollution was conducted to provide basic data for later treatment.Using high?purity germanium γ energy spectrometer and ICP?MS respectively measure the content of natural radionuclides and heavy metals in soil samples from the plant area,and measure the γ air absorption dose rate at the same sampling point.The results showed that the variation range of γ air absorption dose rate was 113~4004 nGy/h in the plant area,and the waste residue stacking area was significantly higher;The contents of 238U,232Th,226Ra,and 40K in soil samples were 80.8~1990.2,78.4~14372.4,68.2~6935.0,and 625.4~2698.4 Bq/kg,respectively.Among the eight heavy metals measured,As exceeded the soil remediation standard seriously,with a maximum of 263.83 mg/kg.Zn and Pb also exceeded the standard to some extent.The pH values of the soil and waste residue in the plant area meet the requirements of soil remediation standards for contaminated sites,while the combined contamination of radioactive and heavy metals in the soil was relatively serious.Detailed site investigation and soil remediation work should be conducted before development and reuse.

rare earth plantγ air absorbed dose ratenatural radioactivityheavy metals pollution

稀土厂场地 γ空气吸收剂量率 天然放射性 重金属污染

国家自然科学基金广州市教育局高校科研项目广州市科技计划项目

41373117201831803201707010421

2024

环境科学导刊
云南环境科学研究院

环境科学导刊

影响因子:0.525
ISSN:1673-9655
年,卷(期):2024.43(1)
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