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微塑料对磺胺甲恶唑的吸附特性

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以聚氯乙烯和聚乙烯为微塑料代表,探究这两种微塑料对磺胺甲恶唑的吸附动力学及热力学特性。结果表明,聚氯乙烯对磺胺甲恶唑的吸附量较大,准二级模型更适合用于描述两种微塑料对磺胺甲恶唑的吸附动力学过程;聚氯乙烯和聚乙烯对磺胺甲恶唑的吸附热力学过程用Langmuir模型拟合较好,说明吸附过程是单层吸附;两种微塑料对磺胺甲恶唑的吸附过程是一个自发进行,吸热并且熵增的过程。
Adsorption Properties of Sulfamethoxazole on Micro-plastics
In this study,polyvinyl chloride and polyethylene were used as micro-plastics to investigate the adsorptionkinetics and thermodynamic properties of sulfamethoxazole.The results showed that the adsorption capacity of sulfamethoxazole was larger on polyvinyl chloride,and the pseudo-second-order model was more suitable for describing the adsorption kinetics of sulfamethoxazole on the two micro-plastics.The adsorption thermodynamic process of sulfamethoxazole on polyvinyl chloride and polyethylene was well fitted by the Langmuir model,indicating that the adsorption process was monolayer adsorption.The adsorption of sulfamethoxazole by the two micro-plastics was a spontaneous,endothermic and entropy-increasing process.

polyvinyl chloridepolyethylenesulfamethoxazoleadsorption

闫晓娜、李敏、罗静、罗婉均、刘娟、刘艳梅

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西华师范大学,四川南充 637000

聚氯乙烯 聚乙烯 磺胺甲恶唑 吸附

2024

环境科学导刊
云南环境科学研究院

环境科学导刊

影响因子:0.525
ISSN:1673-9655
年,卷(期):2024.43(5)