环境科学导刊2024，Vol.43Issue(5) ：82-85.

昆明市饮用水源地类固醇类雌激素的背景调查

Background Investigation on Steroid Estrogens in the Drinking Water Sources in Kunming

李锐 卞世闻 闫琨 徐小峰 魏天宇 李世刚 周圆
环境科学导刊2024，Vol.43Issue(5) ：82-85.
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  • 维普
  • 万方数据

昆明市饮用水源地类固醇类雌激素的背景调查

Background Investigation on Steroid Estrogens in the Drinking Water Sources in Kunming

李锐 1卞世闻 1闫琨 1徐小峰 1魏天宇 1李世刚 1周圆1
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作者信息

  • 1. 云南省生态环境厅驻昆明市生态环境监测站,云南 昆明 650228
  • 折叠

摘要

采用衍生化法-气相色谱串联质谱法,对昆明市饮用水源地水体的天然雌激素雌酮(Estrone,E1)、雌二醇(17 β-Estradiol,E2)、人工合成的炔雌二醇(17α-ethynylestradiol,EE2)和雌三醇(Estriol,E3)浓度进行检测分析.研究发现,E1、E2、EE2和E3的的方法检出限分别为1.98、1.86、2.57和1.93 ng/L.昆明市主城区六个主要饮用水源地(松华坝、大河、清水海、云龙、宝象河、自卫村水库)的4种雌激素浓度均低于方法检出限,表明类固醇类雌激素未检出.

Abstract

In this paper,derivatization and gas chromatography-tandem mass spectrometry were used to test the concentrations of natural Estrone(E1),estradiol(17β-Estradiol,E2),Estriol(E3)and synthetic ethinyl estradiol(17α-ethynylestradiol,EE2)in the drinking water sources of Kunming.The detection limits of E1,E2,EE2 and E3 were 1.98,1.86,2.57 and 1.93ng/L,respectively.The concentrations of four estrogens in the six main drinking water sources(Songhuba,Dahe,Qingshuihai,Yunlong,Baoxianghe,Ziweicun Reservoir)in the main urban area of Kunming were all lower than the detection limits,indicating that steroid estrogens were not detected.

关键词

类固醇类雌激素/衍生化法-气相色谱-串联质谱法/饮用水源地

Key words

steroid estrogens/derivatization and gas chromatography-tandem mass spectrometry/drinking water source

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出版年

2024
环境科学导刊
云南环境科学研究院

环境科学导刊

影响因子：0.525
ISSN：1673-9655
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