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典型镁硅酸盐类脉石矿物的浮选抑制研究进展

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蛇纹石、滑石和绿泥石是典型的层状镁硅酸盐矿物,三者通常呈组合的方式赋存于硫化矿中。硫化矿浮选过程中,蛇纹石、滑石和绿泥石易进入硫化精矿且恶化浮选环境,造成精矿品质不高、回收率较低等问题,与硫化矿往往难以实现高效分离。目前,针对此类硅酸盐类脉石矿物,如何采用适宜的选矿药剂进行高效选择性抑制,仍然是浮选领域研究的热点与难点。分析了蛇纹石、滑石和绿泥石晶体化学特征与浮游性能的关系,蛇纹石表面荷正电,可用阴离子捕收剂浮选;滑石是分子晶体,天然可浮性较好,常用脂肪酸类和胺类捕收剂浮选;绿泥石天然可浮性仅次于滑石,可用阴阳离子捕收剂浮选。同时综述了无机、有机、新型及组合四个类别抑制剂的研究现状,无机抑制剂已成功应用于工业生产中,新型有机抑制剂的合成和应用是未来研究的重点和热点,组合抑制剂协同抑制机理研究尚待加强。还阐述了各类药剂的作用原理和应用,为新型、高效、绿色抑制剂的筛选与合成指明了方向,为抑制剂的组合使用提供了参考,为硫化矿的高效浮选回收提供了技术支撑。
Research Progress on Flotation Depression of Typical Magnesium Silicate Gangue Minerals
Serpentine,talc and chlorite are typical layered magnesium silicate minerals,which usually occur in sulfide ores in a combined manner.In the flotation process of sulfide ore,serpentine,talc and chlorite are easy to enter the sulfide concentrate and deteriorate the flotation environment,resulting in low concentrate quality and low recovery,and it is often difficult to achieve efficient separation from sulfide ore.At present,for such silicate gangue minerals,how to use suitable beneficiation reagents for efficient selective inhibition is still a hot and difficult point in the field of flotation research.The relationship between the crystal chemical characteristics and the floating performance of serpentine,talc and chlorite is analyzed.The surface of serpentine is positively charged and can be floated by anionic collector.Talcum is a molecular crystal with good natural floatability.Fatty acid and amine collectors are commonly used for flotation.The natural floatability of chlorite is second only to talc,which can be floated by anion and cation collectors.At the same time,the research status of inorganic,organic,new and combined inhibitors is reviewed.Inorganic inhibitors have been successfully applied in industrial production.The synthesis and application of new organic inhibitors are the focus and hotspot of future research.The research on the synergistic inhibition mechanism of combined inhibitors needs to be strengthened.This paper also expounds the action principle and application of various reagents,points out the direction for the screening and synthesis of new,efficient and green inhibitors,provides a reference for the combined use of inhibitors,and provides technical support for the efficient flotation recovery of sulfide ore.

typical magnesium silicateserpentinetalcchloritedepressant

环艳、魏志聪、谢海云、刘洋、瞿俊男

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昆明理工大学 国土资源工程学院,昆明 650093

昆明理工大学 云南省战略金属矿产资源绿色分离与富集重点实验室,昆明 650093

西南联合研究生院,昆明 650051

昆明冶金高等专科学校 冶金与矿业学院,昆明 650033

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典型镁硅酸盐 蛇纹石 滑石 绿泥石 抑制剂

2025

有色金属(选矿部分)
北京矿冶研究总院

有色金属(选矿部分)

影响因子:1.235
ISSN:1671-9492
年,卷(期):2025.(1)