水凝胶紫外光固化建模仿真
Modeling,Simulation and Verification of PEGDA Hydrogel UV Curing
陈义保 1高瑛男 1杨文广 1刘慧彬 1王文豪 1郭庆昊 1王晓雯1
作者信息
- 1. 烟台大学机电汽车工程学院,山东烟台 264005
- 折叠
摘要
利用COMSOL Multiphysics仿真软件对紫外光固化进行建模和仿真,探究了单体浓度、引发剂浓度和氧气浓度对紫外光固化反应速度的影响.仿真结果表明:随着单体浓度和引发剂浓度的增加,反应逐渐加快;而随着氧气浓度的增加,反应先加快而后减慢,即氧阻聚现象.通过PEGDA水凝胶紫外光固化实验验证了单体浓度与反应速度的关系.
Abstract
COMSOL Multiphysics simulation software was used to model and simulate UV-curing,and the influence of monomer concentration,initiator concentration and oxygen concentration on UV-curing reaction speed was ex-plored.It was verified that the reaction gradually accelerated with the increase of monomer concentration and initia-tor concentration,while the reaction first accelerated and then slowed down with the increase of oxygen concentra-tion,namely oxygen inhibition.The relationship of monomer concentration and reaction speed is verified by PEG-DA hydrogel UV curing.
关键词
紫外光固化/聚合反应/自由基/氧阻聚Key words
UV curing/polymerization reaction/free radical/oxygen inhibition引用本文复制引用
基金项目
国家自然科学基金资助项目(61803323)
出版年
2024
国家科技期刊平台
NSTL
万方数据