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水凝胶紫外光固化建模仿真

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利用COMSOL Multiphysics仿真软件对紫外光固化进行建模和仿真,探究了单体浓度、引发剂浓度和氧气浓度对紫外光固化反应速度的影响.仿真结果表明:随着单体浓度和引发剂浓度的增加,反应逐渐加快;而随着氧气浓度的增加,反应先加快而后减慢,即氧阻聚现象.通过PEGDA水凝胶紫外光固化实验验证了单体浓度与反应速度的关系.
Modeling,Simulation and Verification of PEGDA Hydrogel UV Curing
COMSOL Multiphysics simulation software was used to model and simulate UV-curing,and the influence of monomer concentration,initiator concentration and oxygen concentration on UV-curing reaction speed was ex-plored.It was verified that the reaction gradually accelerated with the increase of monomer concentration and initia-tor concentration,while the reaction first accelerated and then slowed down with the increase of oxygen concentra-tion,namely oxygen inhibition.The relationship of monomer concentration and reaction speed is verified by PEG-DA hydrogel UV curing.

UV curingpolymerization reactionfree radicaloxygen inhibition

陈义保、高瑛男、杨文广、刘慧彬、王文豪、郭庆昊、王晓雯

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烟台大学机电汽车工程学院,山东烟台 264005

紫外光固化 聚合反应 自由基 氧阻聚

国家自然科学基金资助项目

61803323

2024

烟台大学学报(自然科学与工程版)
烟台大学

烟台大学学报(自然科学与工程版)

影响因子:0.373
ISSN:1004-8820
年,卷(期):2024.37(3)
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