氨基酸及其衍生物的生物基聚氨酯的制备和性能的研究进展
Research Progress on Preparation and Properties of Bio-Based Polyurethanes from Amino Acid and Its Derivatives
唐国鸿 1赵振 2仲家慧 1徐小玲 1孙莹潞 3盛德鲲 3杨宇明1
作者信息
- 1. 中国科学院长春应用化学研究所,高性能合成橡胶及其复合材料重点实验室,长春 130022;中国科学技术大学,合肥 230026
- 2. 空军装备部驻长春地区军事代表室,长春 130000
- 3. 中国科学院长春应用化学研究所,高性能合成橡胶及其复合材料重点实验室,长春 130022
- 折叠
摘要
生物基原料作为一种可再生资源,与石油基原料相比具有污染小、易回收等特点.使用生物基原料合成聚氨酯的研究已经相当广泛,可以用于聚氨酯合成的生物基原料的种类也非常丰富.氨基酸是一种常用的生物基原料,其结构多样,原料易得,具有良好的反应活性,并且降解产物无毒无害.使用氨基酸作为原料合成生物基材料的方法已经较为常用.对氨基酸及其衍生物在生物基聚氨酯合成中的应用进行了介绍,阐述了氨基酸作为不同部分参与到聚氨酯合成的方法路线以及由氨基酸及其衍生物合成的聚氨酯的结构与性能的关系,并对氨基酸及生物基聚氨酯的未来发展进行了展望.
Abstract
As a kind of renewable resource,bio-based raw materials have the characteristics of less pollution and easy recyclability compared to petroleum-based raw materials.The research on polyurethanes synthesized by bio-based feedstocks has been quite extensive,while a wide range of bio-based materials can be chosen.Amino acid as a kind of bio-based raw material,has various structures and high reactivity with easy access to obtain,whose degradation products are non-toxic and harmless.There are versatile methods to synthesize polyurethanes using amino acid as different components.The application of amino acid and its derivates in bio-based polyurethanes synthesis is reviewed;The relationship between structure and performance of the polyurethanes is expounded.The prospect and directions of future development of amino acid and bio-based polyurethanes is envisioned.
关键词
聚氨酯/生物基材料/氨基酸/结构与性能Key words
Polyurethane/Bio-based material/Amino acids/Structure and performance引用本文复制引用
出版年
2025
国家科技期刊平台
NSTL
万方数据