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煤气化水系统腐蚀与防护研究进展

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阐述了水系统腐蚀机制,其中包括冲刷磨损,气蚀,CO2、H2S、HCOOH等酸性介质引发的电化学腐蚀,Cl-引发的氯化物应力腐蚀以及NH4+、CN-等含氮离子引发的多重腐蚀作用,并介绍了水系统中的腐蚀易发部位.同时,从材质选择、装置/工艺设计和监测管理3方面结合煤气化装置实际调研情况,分析总结了应对腐蚀的防护措施,提出建立设备/管道腐蚀风险智能预测系统,以期为煤气化行业腐蚀现状的改进提供参考.
Research Progress on Corrosion and Protection of Water System for Coal Gasification
As the"blood"circulatory system of coal gasification plant,the water system frequently faces corrosion and leakage problems due to the complex environment with high solid content,corrosive media and high temperature and pressure,which seriously affect the safty of production operation.The corrosion mechanism of the water system was explained,which included erosive wear,cavitation,electro-chemical corrosion triggered by CO2,H2S,HCOOH and other acidic media,chloride stress corrosion in-duced by Cl-,and multiple corrosion caused by NH4+,CN-and other nitrogen ions.The corrosion-prone sites of the water system were also introduced.Moreover,combined with the actual research of coal gas-ification devices,the protective measures against corrosion were analyzed and summarized in term of the material selection,device/process design and monitoring management.Establishing an intelligent cor-rosion risk prediction system for equipment/pipeline was proposed.These strategies shed light on im-provement of corrosion status in coal gasification industry.

coal gasificationwater systemcorrosionprotection

刘静远、臧庆安、孙长军、张翠清、李晓峰

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北京低碳清洁能源研究院 北京 102211

国家能源集团化工部 北京 100011

国能新疆化工有限公司 乌鲁木齐 831404

煤气化 水系统 腐蚀 防护

国家能源集团科技创新项目

GJNY-22-28

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(1)
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