首页|TP2紫铜在工业环境中腐蚀行为的研究

TP2紫铜在工业环境中腐蚀行为的研究

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通过结合表征测试、腐蚀失重测试以及电化学测试方法,并模拟TP2紫铜在工业生产中的环境,以分析材料在工业环境中的腐蚀行为.结果表明,与乙酸气氛相比,TP2铜在含有甲酸的腐蚀性气氛的作用下表现出更严重的腐蚀倾向,并且有机酸浓度的增加使材料的腐蚀更加严重.此外,有机酸大气和SO2污染物的结合对TP2紫铜表面造成了更严重的破坏,SO2污染物含量的增加也使情况变得更为严重.与乙酸气氛和SO2污染物的组合相比,甲酸气氛和SO2污染物的组合对TP2紫铜表面表现出严重而复杂的腐蚀行为.
Corrosion Behavior of TP2 Red Copper in Simulated Organic Acids Containing Industrial Environments
With excellent electrical and thermal conductivity,TP2 copper has a wide range of applica-tions in industrial production process.During the practical production process,a large amount of organic acid pollutants containing carboxylic acid ions will be generated.Meanwhile,as a result of the defects of TP2 copper and the impact of moisture and corrosive media in the external environment,the content of or-ganic acid pollutants in operating ambient of TP2 copper is at the high level,which may accelerate the oc-currence of organic acid corrosion on the surface of TP2 copper.In order to simulate the organic acids in-duced corrosion behavior of TP2 copper in industrial environments,the TP2 copper was assessed via im-mersion tests in solutions with different organic acid concentrations temperature-cyclically,by means of measurements of mass loss Tafel polarization and electrochemical impedance,as well as SEM character-ization.The results show that in comparison to the acetic acid containing atmosphere,TP2 copper exhibits stronger corrosion tendency in the formic acid containing ones,while the higher the organic acid concentra-tion,the much severe the corrosion of the TP2 copper.In addition,the combination of the organic acid con-taining atmosphere and SO2 pollutants may cause much severe corrosion damage of the TP2 copper sur-face,and the higher content of the SO2 pollutants,the severe the corrosive conditions.Besides,much se-vere corrosion and complexity of the corrosion behavior emerged on the surface of the TP2 copper in the atmosphere of co-existance of SO2 pollutants and with formic acid rather than that with acedic acid.

TP2 copperorganic acidsSO2 contaminantselectrochemical behavior

何逸、郑传波、戚浩宇、刘珍光

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江苏科技大学冶金工程学院 苏州 215000

江苏科技大学材料科学与工程学院 镇江 212000

TP2紫铜 有机酸 SO2污染物 电化学行为

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(1)
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