首页|轧制对ZM5镁合金腐蚀性能的影响

轧制对ZM5镁合金腐蚀性能的影响

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采用析氢、失重、电化学阻抗谱(EIS)、动态电位极化测试、XRD和SEM等方法对比研究了轧制前后ZM5镁合金腐蚀性能和微观组织的变化,并通过第一性原理分析研究了合金不同微观组织的电子功函数,探究轧制对ZM5镁合金腐蚀性能的影响.结果表明,轧制使ZM5发生明显的择优取向,轧制后ZM5的腐蚀失重、析氢量都显著下降,而极化电阻明显上升,表明轧制态镁合金的耐蚀性优于铸造镁合金.模拟计算结果表明α相的重排提高了轧制合金的电子功函数.
Influence of Rolling on Corrosion Behavior of ZM5 Mg-alloy
The corrosion performance and microstructure of ZM5 Mg-alloy before and after rolling were comparatively studied by hydrogen evolution measurement,mass loss method,electrochemical im-pedance spectroscopy(EIS),dynamic potential polarization measurement,XRD and SEM.The electron work function of different microstructures was numerically simulated through first principle analysis.The results show that rolling causes an obvious preferred orientation for ZM5 Mg-alloy.The corrosion mass loss and hydrogen evolution of ZM5 Mg-alloy decrease significantly after rolling,while the polarization re-sistance increases obviously.These all indicated that the corrosion resistance of the rolled ZM5 Mg-alloy is better than that of the cast one.The simulation results show that the rearrangement of α-phase enhanc-es the electronic work function of the Mg-alloy.

Mg-alloyrollingcorrosion behaviorfirst-principleselectron work function

宋东东、万红霞、徐栋、周倩

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华北电力大学电站能量传递转化与系统教育部重点实验室 北京 102206

中国石油大学(北京)新能源与材料学院 北京 102249

镁合金 轧制态 腐蚀行为 第一性原理 电子功函数

国家自然科学基金国家自然科学基金中央高校基本科研业务费专项

51701055521011122023MS011

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(1)
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