首页|稀土 La对钴基高温合金GH5188在1100 ℃下空气中氧化行为的影响

稀土 La对钴基高温合金GH5188在1100 ℃下空气中氧化行为的影响

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研究了 La含量对GH5188高温合金在1100℃空气中抗氧化性能的影响,并分析了 La的作用机制.结果表明,合金氧化膜主要成份是Cr2O3和MnCr2O4,氧化动力学可近似用抛物线规律来描述.适量La的加入有助于合金形成连续、致密且稳定的氧化膜Cr2O3,提高了氧化膜与合金基体的粘附性,改善了 GH5188高温合金的抗氧化性能.但随着La含量的提高,合金的抗氧化性能会降低,La的最佳含量范围为0.029%~0.060%.
Effect of Rare Earth La on High Temperature Oxidation of Cobalt-based Superalloy GH5188 at 1100℃
The isothermal oxidation behavior of GH5188 superalloy at 1100℃ was studied by means of intermittent weighting,SEM and XRD.The results show that the main components of the formed oxide scale are Cr2O3 and MnCr2O4.The oxidation behavior can be approximated by parabolic law.The addition of La can help the alloy to form a continuous,compact and stable oxide scale of Cr2O3,improve the adhe-sion between the oxide scale and the alloy matrix,therewith enhance the high temperature oxidation re-sistance of GH5188 superalloy.However,with the increase of La content,the high temperature oxidation resistance of the alloy will decrease,the high temperature oxidation resistance of GH5188 alloy can be improved effectively only by adding proper amount of La(0.029%-0.060%).

cobalt base alloyGH5188high temperature oxidationrare earth element

王爽、王资兴、程晓农、罗锐

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江苏大学材料科学与工程学院 镇江 212013

江苏集萃先进金属材料研究所有限公司 苏州 215500

钴基合金 GH5188 高温氧化 稀土元素

新金属材料国家重点实验室项目

2022-Z21

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(1)
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