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高温高压CO2环境中超级13Cr不锈钢点蚀有限元模拟

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采用腐蚀浸泡实验和有限元模拟研究了超级13Cr不锈钢在高温高压CO2环境中的点蚀行为,重点分析了腐蚀时间、温度和CO2分压对点蚀的影响.结果表明:高温高压腐蚀实验与有限元模拟的点蚀深度较为吻合,且平均点蚀深度随着浸泡时间、温度和CO2分压的增大而增大.有限元模拟可知点蚀坑内部由于阳离子水解使得内部酸化,并且pH随着温度降低和CO2分压的增加而下降.此外,点蚀坑内Fe2+浓度随着腐蚀时间的延长和温度的提高而增加,但CO2分压对其影响不大.
Finite Element Simulation of Pitting Corrosion of Super 13Cr Stainless Steel in High-temperature and High-pressured CO2 Containing Artificial Formation Waters
The pitting growth behavior of super 13Cr stainless steel in high-temperature and high-pressured CO2 containing artificial formation waters was comparatively assessed via immersion corrosion test and finit element simulation,focusing on the effect of corrosion time,temperature and partial pres-sure of CO2 on pitting corrosion.The results show that the pitting depth of super 13Cr stainless steel after high-temperature and high-pressure corrosion tests is consistent with that of finite element simulation,and the average pitting depth increases with the increase of immersion time,temperature and CO2 partial pressure.The finite element simulation shows that the interior of the pit is acidified due to cationic hydroly-sis,and the pH value decreases with the decrease of temperature and the increase of CO2 partial pres-sure.In addition,Fe2+concentration inside the pit increases with the increase of corrosion time and tem-perature while the partial pressure of CO2 has little effect.

super 13Cr stainless steelpittingfinite element simulationhigh temperature and pres-sure

凌东、何坤、余靓、董立谨、张华礼、李玉飞、王勤英、张智

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西南石油大学新能源与材料学院 成都 610500

国家管网集团西南管道兰成渝输油分公司 成都 610000

中国石油西南油气田分公司工程技术研究院 德阳 618300

西南石油大学石油与天然气工程学院 成都 610500

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超级13Cr不锈钢 点蚀 有限元模拟 高温高压

国家自然科学基金中国石油-西南石油大学创新联合体科技合作项目

520012642020CX040100

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(2)
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