中国腐蚀与防护学报2024,Vol.44Issue(2) :355-364.DOI:10.11902/1005.4537.2023.105

某燃气轮机燃烧室合金高温蒸汽氧化行为研究

Oxidation Behavior in Air-steam Mixed Atmosphere at 1000℃ of Four Typical High-temperature Alloys for Gas Turbine

梁志远 张超 曲劲宇 何建元 郭亭山 徐一鸣
中国腐蚀与防护学报2024,Vol.44Issue(2) :355-364.DOI:10.11902/1005.4537.2023.105

某燃气轮机燃烧室合金高温蒸汽氧化行为研究

Oxidation Behavior in Air-steam Mixed Atmosphere at 1000℃ of Four Typical High-temperature Alloys for Gas Turbine

梁志远 1张超 2曲劲宇 2何建元 2郭亭山 1徐一鸣1
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作者信息

  • 1. 西安交通大学能源与动力工程学院 西安 710049
  • 2. 中国船舶集团有限公司第七○三研究所船舶与海洋特种装备和动力系统国家工程研究中心 哈尔滨 150078
  • 折叠

摘要

采用蒸汽氧化实验与热力学理论计算研究了DD5,K447A,GH3230以及GH3536共计4种燃气轮机用典型高温合金在高温蒸汽中的氧化行为.在1000℃下含10%H2O的空气中,合金GH3230和K447A氧化增重遵循抛物线氧化规律,合金DD5和GH3536出现失重情况.合金K447A与GH3230表面形成了 Cr2O3和A12O3为主的氧化产物,其中合金GH3230因Al含量较低而发生内氧化现象.DD5表面发生Al2O3氧化膜剥落,而GH3536出现氧化物挥发.结果表明,4种合金的抗蒸汽氧化性能排序为K447>GH3230>DD5>GH3536.

Abstract

The use of doped hydrogen or pure hydrogen as fuel poses a severe test to the key struc-tural components of gas turbines,especially the resistance of materials to steam oxidation.The high-tem-perature steam oxidation behavior of 4 typical high temperature alloys,namely DD5,K447A,GH3230 and GH3536 for gas turbine in a mixed flow of air with 10%steam at 1000℃ was studied by means of mass change measurement and thermodynamic theoretical calculation.It follows that the GH3230 and K447A alloys showed an oxidation mass gain and followed a parabolic law,while the alloys DD5 and GH3536 showed oxidation mass loss on the contrary.The oxidation products formed on K447A and GH3230 alloy were mainly layered Cr2O3 and Al2O3 scales.The spallation of Al2O3 oxide scales occurred on the surface of DD5 alloy,while oxide volatilization was found on GH3536 alloy.In sum,the steam oxida-tion resistance of the four alloys may be ranked as following:K447>GH3230>DD5>GH3536.

关键词

高温合金/蒸汽氧化/燃烧工况/燃气轮机

Key words

superalloys/steam oxidation/combustion condition/gas turbine

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基金项目

创新工程项目(211-XXXX-N106-01-04)

自立科技研发专项(202206Z)

国家科技重大专项(J2019-Ⅲ-0012-0055)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量25
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