中国腐蚀与防护学报2024,Vol.44Issue(2) :365-371.DOI:10.11902/1005.4537.2023.174

用于大气环境的电化学传感器的腐蚀性能研究

Corrosion Performance of Electrochemical Sensors for Atmospheric Environments

李婷玉 魏洁 陈楠 万晔 董俊华
中国腐蚀与防护学报2024,Vol.44Issue(2) :365-371.DOI:10.11902/1005.4537.2023.174

用于大气环境的电化学传感器的腐蚀性能研究

Corrosion Performance of Electrochemical Sensors for Atmospheric Environments

李婷玉 1魏洁 2陈楠 2万晔 3董俊华2
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作者信息

  • 1. 中国科学院金属研究所 沈阳 110016;沈阳建筑大学材料科学与工程学院 沈阳 110168
  • 2. 中国科学院金属研究所 沈阳 110016
  • 3. 沈阳建筑大学材料科学与工程学院 沈阳 110168
  • 折叠

摘要

构造了一种用于监测大气腐蚀的金属材料的电化学传感器,分别选用低合金钢和铜导电漆两种具有不同电位的金属材料,基于电偶腐蚀原理组成传感器的两个电极,两个电极之间以薄的有机硅绝缘膜相隔,传感器与大气薄液膜介质形成一个电化学腐蚀系统.在两个金属电极之间有液膜产成时,就会形成一个腐蚀电池,并产生电偶腐蚀电流,通过监测这种电偶电流以反映环境中材料的腐蚀状态.本文采用新型电化学传感器,同时借助电化学工作站和高精度电子天平,研究了绝缘膜厚度、液膜厚度、温度、相对湿度及阴阳极面积比等因素对电偶电流的影响规律,并证实了新型电化学传感器具有很高的灵敏度,可用于薄液膜下大气腐蚀的监测.

Abstract

An electrochemical sensor for monitoring atmospheric corrosion of metallic materials was constructed.Two metallic materials with different corrosion potentials,i.e.low alloy steel and copper con-ductive paint,were chosen to form the two electrodes of the sensor based on the principle of galvanic cor-rosion.The two electrodes are separated by a thin silicone insulating film,and thus an electrochemical corrosion system may be established by the two electrodes while which was covered by a thin liquid film came from the atmosphere,correspondingly,galvanic corrosion current is generated.This galvanic cur-rent is monitored to reflect the corrosion state of the material in the environment.A new type of electro-chemical sensor was used to study the influence of factors such as insulation film thickness,liquid film thickness,temperature,relative humidity,and cathode to anode area ratio on the galvanic current with the assistance of an electrochemical workstation and a high-precision electronic balance.It is confirmed that the new electrochemical sensor has high sensitivity and can be used for monitoring the atmospheric corrosion process under thin liquid film.

关键词

大气腐蚀/传感器/实时监测/电偶电流

Key words

atmospheric corrosion/sensor/real-time monitoring/galvanic current

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基金项目

辽宁省科技重大专项(2020JH1/10100001)

国家科技基础资源调查专项(2019FY101401)

国家科技基础资源调查专项(2019FY101402)

中国科学院-泰国科技发展书名合作研究项目(174321KYSB20210004)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量26
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