中国腐蚀与防护学报2024,Vol.44Issue(2) :396-404.DOI:10.11902/1005.4537.2023.159

植酸锌的制备及其对Q235钢腐蚀行为的影响

Preparation of Zinc Phytate and Its Effect on Corrosion Behavior of Carbon Steel

周兰欣 张丽萍 汤燕 陈柯宇 周剑军 师超 邵亚薇 刘光明
中国腐蚀与防护学报2024,Vol.44Issue(2) :396-404.DOI:10.11902/1005.4537.2023.159

植酸锌的制备及其对Q235钢腐蚀行为的影响

Preparation of Zinc Phytate and Its Effect on Corrosion Behavior of Carbon Steel

周兰欣 1张丽萍 1汤燕 1陈柯宇 1周剑军 1师超 2邵亚薇 3刘光明1
扫码查看

作者信息

  • 1. 南昌航空大学江西省金属材料微结构调控重点实验室 南昌 330063
  • 2. 南昌航空大学江西省金属材料微结构调控重点实验室 南昌 330063;哈尔滨工程大学材料科学与化学工程学院 哈尔滨 150001
  • 3. 哈尔滨工程大学材料科学与化学工程学院 哈尔滨 150001
  • 折叠

摘要

采用磷酸、植酸、氯化锌制备磷酸锌和植酸锌,通过扫描电子显微镜(SEM)、能谱分析(EDS)、红外光谱(FT-IR)和热重(TG)等手段对制备的磷酸锌和植酸锌进行表征,通过滴定实验分析磷酸锌和植酸锌在水溶液中的溶解度.根据Tafel极化法、电化学阻抗法和腐蚀浸泡实验分析了磷酸锌和植酸锌浸出液中Q235钢的腐蚀特性.结果表明:制备的磷酸锌为非均匀大小的微米片状结构,厚度在0.5-1 pm之间,植酸锌为团聚状粉末状颗粒,粒径在2~5 pm之间;植酸锌在浸出2 h以后,溶液中植酸根含量达到饱和,对Q235钢的缓蚀效率约在90%,表现出良好的缓蚀性能.

Abstract

The performance-based study on anticorrosive pigment is of significance to the develop-ment of new pigment for anticorrosive coatings.Zinc phosphate and zinc phytate were prepared from phosphoric acid,phytic acid and zinc chloride.Then the two pigments were characterized by scanning electron microscopy(SEM),energy dispersive spectroscopy(EDS),thermogravimetry analysis(TG)and infrared spectroscopy(FT-IR).The solubility of zinc phosphate and zinc phytate in aqueous solution was analyzed by titration test.The corrosion characteristics of Q235 carbon steel in extracting solutions of zinc phosphate and zinc phytate were examined respectively by Tafel polarization method,electrochemi-cal impedance spectroscopy(EIS)and immersion test.The results showed that the zinc phosphate pres-ents micron-sheet like structure of non-uniform size with thickness in the range of 0.5-1 μm,and the zinc phytate was agglomeration particle with a particle size of 2-5 μm.While after extracting for 2 h,the con-tent of zinc phytate was basically saturated,and it showed that zinc phytate had excellent inhibition ef-fect,which could slow down the corrosion of Q235 steel with inhibition efficiency up to about 90%.

关键词

Q235钢/腐蚀/植酸锌/缓蚀性能

Key words

Q235 steel/corrosion/zinc phytate/inhibition performance

引用本文复制引用

基金项目

国家自然科学基金(52001155)

江西省自然科学基金(20212BAB214038)

博士启动基金(EA201901056)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量27
段落导航相关论文