首页|钢筋表面双功能磷酸氢钛改性的硅溶胶涂层研究

钢筋表面双功能磷酸氢钛改性的硅溶胶涂层研究

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制备了一种用于钢筋表面的硅溶胶涂层,以水玻璃为前驱体,在涂层制备中引入α-磷酸氢钛(α-TiP)填料,采用XRD、FT-IR、SEM以及离子色谱仪等对α-TiP的结构形貌及离子交换能力进行了表征,并采用XRD、FT-IR、SEM、电化学测试等对涂层的结构形貌及防腐蚀性能进行分析研究.结果表明,α-TiP的离子交换功能可吸纳水玻璃中存在的游离Na+,制备得到的硅溶胶涂层中含有片状α-TiP填料可有效提高涂层的阻隔性能,进而提升硅溶胶涂层对钢筋腐蚀的防护性能,且当添加量为0.4g时涂层防护性能最好.
Silica Sol Coating Modified by Bifunctional Titanium Phosphate for Reinforce Bars
A silica sol coating for the surface of steel bars was prepared via mechanical blending and ultrasonic dispersion with water glass as the film precursor and α-Titanium hydrogen phosphate(α-TiP)as fillers,since the α-TiP is a cationic layered compound with excellent ion exchange performance.The structural morphology and ion exchange ability of α-TiP,as well as the structural morphology and corro-sion resistance of the coating were assessed by means of XRD,FT-IR,SEM,ion chromatography,and electrochemical measurement respectively.The results indicate that with ion exchange function the α-TiP can absorb free sodium ions within the water glass,and the prepared silica sol coating contains flakes ofα-TiP filler can effectively improve the barrier performance of the coating,thereby enhance the protective performance of the silica sol coating against steel corrosion,whilst the coating has the best protective per-formance when the addition amount of α-TiP is 0.4 g.

α-titanium hydrogen phosphateion exchange fillerssilica solcoating

赵鹏、郝春艳、杨胜杰、于金山、武爽、于奔、张俊喜

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国网天津市电力公司电力科学研究院 天津 300384

天津市电力物联网企业重点实验室 天津 300384

上海电力大学电力材料防护与新材料上海市重点实验室 上海 200090

天津送变电工程有限公司 天津 300000

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α-磷酸氢钛 离子交换填料 硅溶胶 涂层

国家电网天津市电力公司科技项目

KJ21-1-12

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(2)
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