中国腐蚀与防护学报2024,Vol.44Issue(2) :413-421.DOI:10.11902/1005.4537.2023.145

钢筋表面双功能磷酸氢钛改性的硅溶胶涂层研究

Silica Sol Coating Modified by Bifunctional Titanium Phosphate for Reinforce Bars

赵鹏 郝春艳 杨胜杰 于金山 武爽 于奔 张俊喜
中国腐蚀与防护学报2024,Vol.44Issue(2) :413-421.DOI:10.11902/1005.4537.2023.145

钢筋表面双功能磷酸氢钛改性的硅溶胶涂层研究

Silica Sol Coating Modified by Bifunctional Titanium Phosphate for Reinforce Bars

赵鹏 1郝春艳 1杨胜杰 2于金山 1武爽 3于奔 1张俊喜2
扫码查看

作者信息

  • 1. 国网天津市电力公司电力科学研究院 天津 300384;天津市电力物联网企业重点实验室 天津 300384
  • 2. 上海电力大学电力材料防护与新材料上海市重点实验室 上海 200090
  • 3. 天津送变电工程有限公司 天津 300000
  • 折叠

摘要

制备了一种用于钢筋表面的硅溶胶涂层,以水玻璃为前驱体,在涂层制备中引入α-磷酸氢钛(α-TiP)填料,采用XRD、FT-IR、SEM以及离子色谱仪等对α-TiP的结构形貌及离子交换能力进行了表征,并采用XRD、FT-IR、SEM、电化学测试等对涂层的结构形貌及防腐蚀性能进行分析研究.结果表明,α-TiP的离子交换功能可吸纳水玻璃中存在的游离Na+,制备得到的硅溶胶涂层中含有片状α-TiP填料可有效提高涂层的阻隔性能,进而提升硅溶胶涂层对钢筋腐蚀的防护性能,且当添加量为0.4g时涂层防护性能最好.

Abstract

A silica sol coating for the surface of steel bars was prepared via mechanical blending and ultrasonic dispersion with water glass as the film precursor and α-Titanium hydrogen phosphate(α-TiP)as fillers,since the α-TiP is a cationic layered compound with excellent ion exchange performance.The structural morphology and ion exchange ability of α-TiP,as well as the structural morphology and corro-sion resistance of the coating were assessed by means of XRD,FT-IR,SEM,ion chromatography,and electrochemical measurement respectively.The results indicate that with ion exchange function the α-TiP can absorb free sodium ions within the water glass,and the prepared silica sol coating contains flakes ofα-TiP filler can effectively improve the barrier performance of the coating,thereby enhance the protective performance of the silica sol coating against steel corrosion,whilst the coating has the best protective per-formance when the addition amount of α-TiP is 0.4 g.

关键词

α-磷酸氢钛/离子交换填料/硅溶胶/涂层

Key words

α-titanium hydrogen phosphate/ion exchange fillers/silica sol/coating

引用本文复制引用

基金项目

国家电网天津市电力公司科技项目(KJ21-1-12)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量45
段落导航相关论文