中国腐蚀与防护学报2024,Vol.44Issue(2) :429-436.DOI:10.11902/1005.4537.2023.093

形变强化和逆相变细晶强化对Fe-18Cr-8Ni钢耐腐蚀性能的影响

Effect of Deformation Strengthening and Phase Reversion Grain Refinement Strengthening on Corrosion Resistance of Fe-18Cr-8Ni Steel

王智慧 吴雷 姜懿珊 张弦 万响亮 李光强 吴开明
中国腐蚀与防护学报2024,Vol.44Issue(2) :429-436.DOI:10.11902/1005.4537.2023.093

形变强化和逆相变细晶强化对Fe-18Cr-8Ni钢耐腐蚀性能的影响

Effect of Deformation Strengthening and Phase Reversion Grain Refinement Strengthening on Corrosion Resistance of Fe-18Cr-8Ni Steel

王智慧 1吴雷 1姜懿珊 2张弦 1万响亮 1李光强 1吴开明3
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作者信息

  • 1. 武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室 武汉 430081
  • 2. 武汉科技大学绿色制造工程研究院 武汉 430081
  • 3. 武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室 武汉 430081;武汉科技大学高性能钢铁材料及其应用省部共建协同创新中心 武汉 430081
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摘要

利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)、电子背散射衍射(EBSD)和电化学工作站等对奥氏体不锈钢的微观组织及电化学腐蚀行为进行了分析.结果表明,形变强化和逆相变细晶强化提高了奥氏体不锈钢在3.5%NaCl溶液中的耐点蚀性能,晶粒细化导致晶界密度的增加,提高了 Cr在晶界中的扩散速率,从而提高钝化膜的稳定性与致密性.经过敏化处理后形变强化和逆相变细晶强化提高了奥氏体不锈钢的耐晶间腐蚀能力.碳化铬析出物周围形成的贫铬区降低了耐晶间腐蚀性能,而在超细晶/细晶组织中Cr的快速扩散促进了贫铬区的快速愈合,提高了耐晶间腐蚀性能.

Abstract

Cold rolling and reverse phase transformation are the main methods to enhance the yield strength of austenitic stainless steel.Therefore,the effect of deformation strengthening and grain refine-ment strengthening on the microstructure and corrosion behavior of Fe-18Cr-8Ni austenitic stainless steel was characterized by SEM,TEM,EBSD,electrochemical workstation and other technical character-ization means.The results show that the deformation strengthening and the inverse phase transformation induced grain refinement strengthening could enhance the pitting resistance of austenitic stainless steel in 3.5%NaCl solution,grain refinement led to an increase in grain boundary density,which promote the diffusion rate of Cr at grain boundaries,thereby improving the stability and compactness of the passiv-ation film.After sensitization treatment,deformation strengthening and inverse phase transformation in-duced grain refinement strengthening could enhance the intergranular corrosion resistance of austenitic stainless steel.The appearance of Cr-depletion zone around chromium carbide precipitates will deterio-rate the intergranular corrosion resistance of the steel,while the rapid diffusion of Cr in ultrafine grain/fine grain structure will promoted the rapid healing of the passivation film on the Cr-depletion zone,thus the intergranular corrosion resistance of the steel may be improved.

关键词

奥氏体不锈钢/形变强化/细晶强化/晶间腐蚀

Key words

austenitic stainless steel/deformation strengthening/fine grained strengthening/inter-granular corrosion

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基金项目

国家自然科学基金(U20A20277)

广西壮族自治区科技重大专项(AA22068080)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量29
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