中国腐蚀与防护学报2024,Vol.44Issue(3) :612-622.DOI:10.11902/1005.4537.2023.182

K452合金表面CVD渗铝涂层制备温度对其750℃硫酸盐热腐蚀行为的影响

Effect of Coating Process Temperatures on Hot Corrosion Be-havior Induced by Deposit of Sulfates Salts in Air at 750℃ for CVD Aluminized Coatings on K452 Superalloy

徐佳新 耿树江 王金龙 王福会 孙清云 吴勇 夏思瑶
中国腐蚀与防护学报2024,Vol.44Issue(3) :612-622.DOI:10.11902/1005.4537.2023.182

K452合金表面CVD渗铝涂层制备温度对其750℃硫酸盐热腐蚀行为的影响

Effect of Coating Process Temperatures on Hot Corrosion Be-havior Induced by Deposit of Sulfates Salts in Air at 750℃ for CVD Aluminized Coatings on K452 Superalloy

徐佳新 1耿树江 1王金龙 1王福会 1孙清云 2吴勇 2夏思瑶2
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作者信息

  • 1. 东北大学 沈阳材料科学国家研究中心东北大学联合研究分部 沈阳 110819
  • 2. 中国机械总院集团武汉材料保护研究所有限公司 武汉 430030
  • 折叠

摘要

采用化学气相沉积(CVD)技术在K452合金表面沉积渗铝涂层,沉积温度分别为850、950和1050℃.研究了沉积温度对CVD渗铝涂层在750℃空气中表面沉积Na2SO4及Na2SO4+NaCl环境下热腐蚀行为的影响.采用扫描电子显微镜(SEM)、X射线能谱仪(EDS)和X射线衍射仪(XRD)对腐蚀前和后的试样进行截面形貌观察和物相结构分析.结果表明,在750℃下表面沉积Na2SO4及Na2SO4+NaCl热腐蚀50h后,3种涂层试样均表现出了较K452合金更好的抗热腐蚀性能,且涂层的抗热腐蚀性能随着涂层沉积温度的增加而增强.

Abstract

Aluminized coatings were deposited on K452 superalloy by chemical vapor deposition(CVD)technique at the temperatures 850,950 and 1050℃,respectively.The effect of deposition temper-ature on the corrosion behavior of K452 alloys without and with CVD aluminized coatings was compara-tively investigated beneath deposits of Na2SO4 and Na2SO4+NaCl(3±0.2 mg/cm2),respectively in air at 750℃.Then their cross-sectional morphologies and phase structures were characterized by SEM/EDS and XRD.The results showed that all the aluminized coatings exhibited better corrosion resistance to the deposits of Na2SO4 and Na2SO4+NaCl as compared to the bare K452 alloy after 50 h of corrosion.Notably,the corrosion resistance of the coatings was increased with the increase in deposition temperatures.

关键词

CVD渗铝涂层/沉积温度/Na2SO4腐蚀/Na2SO4+NaCl腐蚀

Key words

CVD aluminized coatings/deposition temperature/Na2SO4-induced corrosion/Na2SO4+NaCl-induced corrosion

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基金项目

国家重点研发计划(2020YFB2010400)

湖北省重点研发计划(2021BAA210)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量41
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