首页|Inconel 718及其渗铝涂层在Na2SO4+5%NaCl混合盐膜下的热腐蚀行为

Inconel 718及其渗铝涂层在Na2SO4+5%NaCl混合盐膜下的热腐蚀行为

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采用化学气相沉积(CVD)工艺在镍基高温合金Inconel 718上制备了铝化物涂层,研究了Inconel 718合金及其渗铝涂层在750,850和950℃空气中Na2SO4+5%(质量分数)NaCl混合盐膜下的热腐蚀行为.结果表明:基体表现出较差的抗腐蚀性能,且温度越高腐蚀越严重;腐蚀初期表面腐蚀产物主要由Cr2O3和Fe2O3组成,而随着腐蚀时间增加,尖晶石为主要腐蚀产物.此外,基体合金在850和950℃时的腐蚀膜疏松多孔,观察到开裂和剥落,抗腐蚀能力差;而渗铝涂层表现良好,腐蚀期间表面会形成Al2O3膜,极大提高了基体合金的抗腐蚀性能.虽然当腐蚀温度升高或腐蚀时间增加时,涂层会发生明显退化,且会导致腐蚀膜出现裂纹、孔洞等缺陷,其与涂层结合不紧密,但仍能在很大程度上有效保护基体.
Hot Corrosion Behavior of Inconel 718 Without and With Aluminide Coating in Air Beneath a Thin Film of Salt Mixture of Na2SO4+5%NaCl
Aluminide coating was prepared on Inconel 718 superalloy by chemical vapor deposition(CVD).The hot corrosion behavior of Inconel 718 without and with aluminide coating beneath a thin film of salt mixture of Na2SO4(95%)+NaCl(5%)in air at 750,850 and 950℃ was studied respectively.The results indicate that Inconel 718 alloy shows poor corrosion resistance,and the higher the temperature,the more serious the corrosion.In the early stage of hot corrosion,the surface corrosion products are mainly composed of Cr2O3 and Fe2O3.As the corrosion time increases,spinel oxide becomes the main corrosion products.In addition,the scale on Inconel 718 alloy formed at 850 and 950℃ is loose and po-rous,while cracking and peeling were observed.For the aluminide coated alloy,it performs well with en-hanced corrosion resistance,while an Al2O3 scale is formed on the coating surface during corrosion.Al-though the coating underwent significant degradation with the increasing corrosion temperature and/or corrosion time.Besides,the formed corrosion scale is not tightly boned to the coating,while the defects such as cracks or voids are observed.Even so,the coating can still protect the substrate effectively to a great extent.

Inconel 718CVD aluminide coatingNa2SO4+5%NaClhot corrosion

胡琪、耿树江、王金龙、王福会、孙清云、吴勇、夏思瑶

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东北大学 沈阳材料科学国家研究中心东北大学联合研究分部 沈阳 110819

中国机械总院集团武汉材料保护研究所有限公司 武汉 430030

Inconel 718 CVD渗铝涂层 Na2SO4+5%NaCl 热腐蚀

国家重点研发计划湖北省重点研发计划

2020YFB20104002021BAA210

2024

中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
年,卷(期):2024.44(3)