中国腐蚀与防护学报2024,Vol.44Issue(3) :707-715.DOI:10.11902/1005.4537.2023.209

油水交替环境中咪唑啉对CO2腐蚀的抑制作用研究

Inhibition of Imidazolines on CO2 Induced Corrosion of Carbon Steel in Oil and Water Alternatively Wetting Conditions

欧阳嘉露 王茜茜 韩霞 王子明
中国腐蚀与防护学报2024,Vol.44Issue(3) :707-715.DOI:10.11902/1005.4537.2023.209

油水交替环境中咪唑啉对CO2腐蚀的抑制作用研究

Inhibition of Imidazolines on CO2 Induced Corrosion of Carbon Steel in Oil and Water Alternatively Wetting Conditions

欧阳嘉露 1王茜茜 1韩霞 2王子明1
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作者信息

  • 1. 厦门大学材料学院 海洋材料腐蚀防护研究中心 厦门 361005
  • 2. 中石化石油工程设计有限公司 东营 257026
  • 折叠

摘要

通过添加两类典型油溶性和水溶性咪唑啉缓蚀剂,检验了其在油水动态润湿环境中对碳钢CO2腐蚀的抑制效果.研究表明,水溶性咪唑啉的缓蚀效果优于油溶性咪唑啉,其缓蚀效果差异主要源于油水界面行为的改变.油溶性咪唑啉分子通过增强油相中自修复作用来提高缓蚀效果;水溶性咪唑啉分子可以有效抑制油水界面水滴的形成和长大等过程,减弱CO2对油膜的破坏作用,增强动态润湿缓蚀效果.

Abstract

Corrosion inhibitor is the most commonly used for corrosion control in oil production,but the relevant inhibition mechanism in complex CO2 containing multiphase flow environment is still unclear.The effect of two typical oil-soluble and water-soluble imidazoline inhibitors on CO2 induced corrosion of carbon steel in oil and water alternatively wetting conditions was investigated.It was found that the corro-sion inhibition effect of the water-soluble imidazoline was better than that of the oil-soluble imidazoline,and the difference was mainly attributed to the performance of interface oil/water.The oil-soluble imidazo-line molecules can improve the inhibition effect by enhancing the self-repair on the oil phase side,while the water-soluble imidazoline molecules can effectively inhibit the generation and growth of water drop-lets at the interface oil/water,weaken the rupture of CO2 to the oil layer,and enhance the corrosion inhibi-tion in dynamic wetting conditions.

关键词

CO2腐蚀/咪唑啉类缓蚀剂/油水交替润湿

Key words

CO2 corrosion/imidazoline inhibitor/oil-water alternate wetting

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基金项目

国家自然科学基金(52271075)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量28
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