中国腐蚀与防护学报2024,Vol.44Issue(5) :1100-1116.DOI:10.11902/1005.4537.2023.391

高熵合金耐蚀性研究进展

Research Progress on Corrosion Resistance of High-entropy Alloys

程永贺 付俊伟 赵茂密 沈云军
中国腐蚀与防护学报2024,Vol.44Issue(5) :1100-1116.DOI:10.11902/1005.4537.2023.391

高熵合金耐蚀性研究进展

Research Progress on Corrosion Resistance of High-entropy Alloys

程永贺 1付俊伟 2赵茂密 3沈云军4
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作者信息

  • 1. 广西民族大学化学化工学院 南宁 530006;广西科学院海洋腐蚀防护研究院 南宁 530007
  • 2. 广西科学院海洋腐蚀防护研究院 南宁 530007;中国科学院海洋研究所 海洋环境腐蚀与生物污损重点实验室 海洋关键材料重点实验室 青岛 266071
  • 3. 广西科学院海洋腐蚀防护研究院 南宁 530007
  • 4. 广西民族大学化学化工学院 南宁 530006
  • 折叠

摘要

和传统合金材料相比,高熵合金具有更优异的耐腐蚀、高温耐磨损以及综合力学性能等,在一些苛刻环境下具有极大的潜在应用价值,因此受到了越来越多的关注.本文聚焦于高熵合金的耐蚀性能.首先,重点讨论了常用的合金元素对BCC、FCC、BCC+FCC和HCP晶体结构的高熵合金在NaCl、酸性溶液介质中耐蚀性能的影响规律.其次,简要说明了金属元素之间的相互作用对高熵合金耐蚀性能产生的影响.讨论了晶粒尺寸、位错密度和晶体结构等微观特征对高熵合金耐蚀性的影响规律,增大晶粒尺寸或减少位错密度,有助于提高其耐蚀性.最后,总结了几种改善高熵合金耐蚀性能的方法,如热处理、阳极处理和添加缓蚀剂等技术,并对高熵合金未来的发展提出了建议和展望.

Abstract

Compared with traditional alloys,high-entropy alloys display bettercorrosion resistance,high-temperature wear resistance and comprehensive mechanical properties.Thus,high-entropy alloys can find their applications in some harsh environments where traditional alloys may not satisfy the re-quirements.This work focuses on the corrosion resistance of high-entropy alloys.The influence of com-monly used alloying elements on the corrosion resistance of high-entropy alloys with BCC,FCC,FCC+BCC and HCP crystal structures in sodium chloride and acidic solution media was discussed.The effect of the interaction between metal elements on corrosion resistance of high-entropy alloys was briefly ex-plained.The influence of grain size,dislocation density,and crystal structure on the corrosion resistance of high-entropy alloys was also discussed.The results show that the corrosion resistance of high-entropy alloys can be improved by increasing grain size or reducing dislocation density.Several methods for im-proving the corrosion resistance of high-entropy alloys such as heat treatment and anodizing treatment,as well as application of corrosion inhibitor,were summarized.Finally,suggestions and prospects for the future development of high-entropy alloys were put forward.

关键词

高熵合金/耐蚀性能/苛刻环境/微观组织/合金元素

Key words

high-entropy alloy/corrosion resistance/harsh environment/microstructure/alloy element

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基金项目

中国科学院海洋研究所启动经费项目(E12822101Q)

广西重点研发计划(桂科AB23026059)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量103
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