中国腐蚀与防护学报2024,Vol.44Issue(5) :1255-1262.DOI:10.11902/1005.4537.2023.337

螺纹钢中MnS夹杂物诱发的局部腐蚀行为

Localized Corrosion Behavior Induced by MnS Inclusions in HRB400E Rebar Steel

韩宇龙 李健 郭丽雅 杨边疆 陆恒昌 韦习成 董瀚
中国腐蚀与防护学报2024,Vol.44Issue(5) :1255-1262.DOI:10.11902/1005.4537.2023.337

螺纹钢中MnS夹杂物诱发的局部腐蚀行为

Localized Corrosion Behavior Induced by MnS Inclusions in HRB400E Rebar Steel

韩宇龙 1李健 2郭丽雅 1杨边疆 3陆恒昌 1韦习成 1董瀚1
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作者信息

  • 1. 上海大学材料科学与工程学院 上海 200444;上海大学(浙江)高端装备基础件材料研究院 嘉兴 314100
  • 2. 陕钢集团产业创新研究院有限公司 汉中 723000
  • 3. 上海大学(浙江)高端装备基础件材料研究院 嘉兴 314100
  • 折叠

摘要

采用全自动夹杂物分析仪、浸泡实验和电子背散射衍射仪(EBSD)等手段研究了HRB400E螺纹钢中不同尺寸MnS夹杂物在Cl-环境中诱发局部腐蚀行为.原位浸泡结果表明:MnS夹杂物尺寸越大,越容易诱发局部腐蚀行为.EBSD结果表明:尺寸大于40 μm2的夹杂物容易引发腐蚀,和周围有较多的小角度晶界和较高的位错密度有关.同时,团簇大尺寸夹杂物共同诱发局部腐蚀形成的蚀坑面积大于单一夹杂物诱发的蚀坑.

Abstract

The effect of MnS inclusions with different sizes on the corrosion behavior of HRB400E re-bar steel in 2%NaCl solution was investigated by means of automatic inclusion analyzer,immersion tests and Electron Backscattered Diffraction.The in-situ immersion test results showed that the localized corro-sion was more easily induced by the relatively larger MnS inclusions than the smaller ones.The EBSD re-sults suggested that corrosion was more likely initiated by inclusions with size above 40 μm2,and this may be related to the presence of more low-angle grain boundaries and higher dislocation densities around them.Meanwhile,compared with the pit induced by a single inclusion,the width of pits initiated by clusters of large-size inclusions were greater.

关键词

MnS/尺寸/螺纹钢/局部腐蚀

Key words

MnS/size/rebars/localized corrosion

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基金项目

国家自然科学基金(42276214)

国家自然科学基金(52201078)

上海市青年科技英才扬帆计划(21YF1412800)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCD北大核心
影响因子:0.819
ISSN:1005-4537
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