中国腐蚀与防护学报2024,Vol.44Issue(5) :1285-1294.DOI:10.11902/1005.4537.2023.365

时效处理对马氏体时效硬化不锈钢显微组织和局部腐蚀性能的影响

Effect of Aging on Microstructures and Localized Corrosion of Custom455 Martensitic Age-hardening Stainless Steel

洪孝木 王永强 李娜 田凯 杜娟
中国腐蚀与防护学报2024,Vol.44Issue(5) :1285-1294.DOI:10.11902/1005.4537.2023.365

时效处理对马氏体时效硬化不锈钢显微组织和局部腐蚀性能的影响

Effect of Aging on Microstructures and Localized Corrosion of Custom455 Martensitic Age-hardening Stainless Steel

洪孝木 1王永强 1李娜 2田凯 1杜娟1
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作者信息

  • 1. 安徽工业大学材料科学与工程学院 马鞍山 243002
  • 2. 安徽工业大学冶金工程学院 马鞍山 243002
  • 折叠

摘要

利用OM、XRD、TEM、电化学等方法研究了时效处理对Custom455马氏体时效硬化不锈钢显微组织和抗点蚀性能的影响.结果表明,经过时效处理后试样的基体组织为板条马氏体和逆转变奥氏体,并有富铜相、Ni3Ti等第二相粒子析出.当时效时间一定、时效温度在400~550℃时,逆转变奥氏体的含量随时效温度的上升而上升,因此试样的抗点蚀性能上升;时效温度升至600℃时,试样中大量析出的第二相粒子导致试样抗点蚀性能降低.在时效温度不变时,时效时间由1h延长至3 h,由于逆转变奥氏体含量变化不明显,且析出相的数量增多、尺寸变大,导致试样抗点蚀性能下降.

Abstract

The effect of aging treatment at 400-500℃ for different times on the microstructure and pitting resistance of Custom455 martensitic age-hardening stainless steel was investigated using OM,XRD,TEM and electrochemical methods.The results show that the microstructure of the ageing-treated steels consists of lath martensite and reversed austenite,and with the change of aging temperature and time,the second phase particles such as Cu-rich phases and Ni3Ti with varying amount and size will be precipitated.For a given aging time,while the aging temperature increased,the amount of reversed aus-tenite will also gradually increase,however the amount and size of Ni3Ti,e-Cu and other second-phase particles will not change obviously,so that the pitting corrosion resistance of the steel increased;when the aging temperature rises to 600℃,a large number of the second-phase particles of Ni3Ti,e-Cu and oth-ers precipitate out,which leads to a decrease in the pitting corrosion resistance of the steel.When the ag-ing temperature is consistent while the aging time rises to 3 h,the amount of reversed austenite in the steel does not change significantly,but the amount and size of Ni3Ti,ε-Cu and other second-phase parti-cles change significantly with the increasing aging time,which also leads to a decrease in the pitting cor-rosion resistance of the steel.

关键词

马氏体时效不锈钢/时效处理/点蚀/逆转变奥氏体/富铜析出相

Key words

Martensitic aging stainless steel/aging treatment/pitting/reversed austenite/copper-rich precipitation phase

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基金项目

国家自然科学基金(52171059)

国家自然科学基金(51971003)

出版年

2024
中国腐蚀与防护学报
中国腐蚀与防护学会 中国科学院金属研究所

中国腐蚀与防护学报

CSTPCDCSCD北大核心
影响因子:0.819
ISSN:1005-4537
参考文献量27
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