首页|Advances in doping strategies for sodium transition metal oxides cathodes:A review

Advances in doping strategies for sodium transition metal oxides cathodes:A review

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The electrochemistry of cathode materials for sodium-ion batteries differs significantly from lithium-ion batteries and offers distinct advantages.Overall,the progress of commercializing sodium-ion batteries is currently impeded by the inherent inefficiencies exhibited by these cathode materials,which include insufficient conductivity,slow kinetics,and substantial volume changes throughout the process of intercalation and deintercalation cycles.Consequently,numerous methodo-logies have been utilized to tackle these challenges,encompassing structural modulation,surface modification,and elemental doping.This paper aims to highlight fundamental principles and strategies for the development of sodium transition metal oxide cathodes.Specifically,it emphasizes the role of various elemental doping techniques in initiating anionic redox reactions,improving cathode stability,and enhancing the operational voltage of these cathodes,aiming to provide readers with novel perspectives on the design of sodium metal oxide cathodes through the doping approach,as well as address the current obstacles that can be overcome/alleviated through these dopant strategies.

sodium-ion batteriestransition metal cathodedoping strategy

Zhijing ZHANG、Haoze ZHANG、Yaopeng WU、Wei YAN、Jiujun ZHANG、Yun ZHENG、Lanting QIAN

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Department of Chemical Engineering,Waterloo Institute of Nanotechnology,University of Waterloo,Waterloo ON N2L 3G1,Canada

School of Mechanical and Automotive Engineering,South China University of Technology,Guangzhou 510640,China

Institute of New Energy Materials Science and Engineering,School of Materials Science and Engineering,Fuzhou University,Fuzhou 350108,China

国家自然科学基金Fujian Provice Super 100 Talents ProgramFujian Provice 100 Talents ProgramFujian Provice Minjiang Scholar Program

22250710676

2024

能源前沿
高等教育出版社

能源前沿

CSTPCDEI
影响因子:0.2
ISSN:2095-1701
年,卷(期):2024.18(2)
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