首页|锰氧化物/明胶基多孔碳球复合催化剂催化分解臭氧性能研究

锰氧化物/明胶基多孔碳球复合催化剂催化分解臭氧性能研究

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目的 制备锰氧化物/明胶基多孔碳球复合催化剂,研究其催化分解臭氧的性能.方法 通过化学共沉积法制备拥有不同孔径特征的锰氧化物负载的明胶基多孔碳球催化剂(Mn-GBC-4,Mn-GBC-1,Mn-GBC-2,Mn-GBC-3),对其微观结构进行X射线衍射、BET比表面积分析、扫描电子显微镜表征,并研究其在分解臭氧时的抗湿性能及寿命.结果 制备的复合催化剂Mn-GBC-1在常温常压、空气相对湿度40%、20 000h-1空速条件下,对臭氧的分解率可达97%,且催化剂寿命具有高稳定性,最高为200 h.结论 制备的锰氧化物/明胶基多孔碳球复合催化剂具有优良的臭氧分解性能,为开发更高效的臭氧分解催化剂提供了新思路.
MnOn/gelatin based carbon beads catalyst for ozone decomposition
Objective To prepare manganese oxides/gelatin based porous carbon beads catalyst,and study its catalytic performance for ozone decomposition.Methods A series of gelatin based porous carbon beads supported MnOn catalysts were prepared by chemical codeposition method(Mn-GBC-4,Mn-GBC-1,Mn-GBC-2,Mn-GBC-3).Characterize its microstructure by XRD,BET,and SEM,and study its moisture resistance and lifespan performance.Results Under normal temperatare and pressure,40%relative humidity and 20 000-1 airspeed,the decomposition rate of ozone reached 97%over Mn-GBC-1,,and the catalyst life showed high stability(~200 h).Conclusion Manganese oxides/gelatin based porous carbon beads catalyst prepared in this study showed excellent ozone decomposition performance and good practical application prospects,and it provided new ideas for developing more efficient ozone decomposition catalysts.

OzoneCatalytic decompositionManganese oxidesGelatin based porous carbon beadCatalyst

慈颖、于鹰畅、王思、于珊珊、张珊

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中国检验检疫科学研究院,北京 100176

臭氧 催化分解 锰氧化物 明胶基多孔碳球 催化剂

国家重点研发计划项目

2021YFC2600503

2024

中国国境卫生检疫杂志
中国质检报刊社

中国国境卫生检疫杂志

CSTPCD
影响因子:0.415
ISSN:1004-9770
年,卷(期):2024.47(3)
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