中国港湾建设2024,Vol.44Issue(3) :39-43,70.DOI:10.7640/zggwjs202403007

P/M和W/C对磷酸镁水泥强度的影响分析

Influence of P/M and W/C on the strength of magnesium phosphate cement

刘欣 赵友帅 唐宇晗 李帅 张海霞 赵鑫 张晓平 辛自洁 岳雪涛
中国港湾建设2024,Vol.44Issue(3) :39-43,70.DOI:10.7640/zggwjs202403007

P/M和W/C对磷酸镁水泥强度的影响分析

Influence of P/M and W/C on the strength of magnesium phosphate cement

刘欣 1赵友帅 1唐宇晗 1李帅 1张海霞 1赵鑫 1张晓平 1辛自洁 1岳雪涛1
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作者信息

  • 1. 山东建筑大学材料科学与工程学院,山东 济南 250101
  • 折叠

摘要

为探究磷镁比(P/M)及水灰比(W/C)对磷酸镁水泥强度的影响和作用机理,对其力学性能进行测试,并结合XRD、SEM和FT-IR等测试手段对其物相组成及微观形貌进行表征和分析.研究结果表明:W/C=0.15时,磷酸二氢钾掺量的降低会使磷酸镁水泥的各龄期抗压强度增强,P/M=1∶4时其3 h强度超过30MPa,而当掺量过高时,3h强度低于20 MPa,其产物MgKPO4.6H20(K-struvite)的生成量减少且试件存在开裂区域;W/C=0.25时,减少MgO的掺量可以提高磷酸镁水泥的强度,P/M=1∶1.5时,3 h的抗压强度接近30 MPa,磷酸镁水泥的水化产物K-struvite形貌结晶完好且排列紧密.

Abstract

In order to explore the effects of phosphorus to magnesium ratio(P/M)and water-cement ratio(W/C)on the strength of magnesium phosphate cement,its mechanical properties were tested,and its phase composition and microscopic morphology were characterized and analyzed by means of XRD,SEM and FTIR.The results show that:When W/C=0.15,the decrease of potassium dihydrogen phosphate content will enhance the compressive strength of magnesium phosphate cement at each age.When P/M=1∶4,the 3 h strength exceeds 30 MPa,while when the content is too high,the 3 h strength is lower than 20 MPa.The amount of MgKPO4·6H2O(K-struvite)was reduced and there were cracking areas in the specimen.When W/C=0.25,the strength of magnesium phosphate cement can be improved by reducing the content of MgO.When P/M=1∶1.5,the compressive strength of magnesium phosphate cement for 3 h is close to 30 MPa,and the K-struvite hydration products of magnesium phosphate cement are intact crystalline and closely arranged.

关键词

P/M/W/C/磷酸镁水泥/抗压强度/水化产物

Key words

P/M/W/C/magnesium phosphate cement/compressive strength/hydration product

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基金项目

山东省重点研发计划(公益性科技公关类)(2019GSF109108)

出版年

2024
中国港湾建设
中国交通建设股份有限公司

中国港湾建设

CSTPCD
影响因子:0.447
ISSN:1003-3688
参考文献量17
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