首页|基于多模式的北京PM2.5组分特征及氧化潜势分析

基于多模式的北京PM2.5组分特征及氧化潜势分析

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于2019年3、7月在中国气象科学研究院站进行PM2。5样品采集与实验分析,并用正交矩阵因子分析法(PMF)模型进行来源解析,发现交通源(19。10%)、二次组分(19。17%)和扬尘源(18。02%)是采样期间PM2。5污染主要来源。在此基础上以每立方米大气体积的抗坏血酸的消耗速率(OPv)表征PM2。5 的氧化潜势。3 月北京的 OPv 值为(210。49±169。00)[pmol/(min·m3)],7 月则为(313。34±131。84)[(pmol/(min m3))。且 OPv 与 Cu(r=0。801)、As(r=0。742)、SO42-(r=0。701)等具有很强的相关性。将多元回归结果和WRF-Chem模型结合,构建了新的氧化潜势预测模型,发现OPv和PM2。5浓度的空间特征存在差异,北京市OPv的浓度最大值出现在东南部。
Analysis of PM2.5 component characteristics and oxidative potential in Beijing based on multi-mode application
PM2.5 samples were collected and analyzed at the station of Chinese Academy of Meteorological Sciences(CAMS)in March and July 2019.PMF(Positive Matrix Factorization)model was used for source analysis,demonstrating that traffic sources(19.10%),secondary components(19.17%)and dust sources(18.02%)were the main sources of PM2.5 pollution during the sampling period in Beijing.On this basis,the oxidative potential of PM2.5 was determined by the consumption rate of ascorbic acid(AA)per cubic meter,referred as OPv.The OPv were(210.49±169.00)[pmol/(min·m3)]and(313.34±131.84)[pmol/min·m3]]in March and July,respectively.OPv had a very strong correlation with Cu(r=0.801),As(r=0.742),SO42(r=0.701).A new OPv prediction model was constructed by the multiple regression results and the WRF-Chem model.It was found that there were differences in the spatial characteristics of OPv and PM2.5 concentrations,and the maximum concentration of OPv in Beijing appeared in the southeast.

PM2.5PMFoxidative potentialmultiple linear regressionWRF-Chemnumerical simulation

滑彤昕、刘蕾、温维、刘晓宇、姜博、马欣、刘育松、邓子凡

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北京科技大学能源与环境工程学院,北京 100083

中国气象科学研究院,北京 100081

北京市生态环境保护研究院,北京 100037

中国气象局地球系统数值预报中心,北京 100081

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PM2.5 正交矩阵因子分析法(PMF) 氧化潜势 多元回归分析 WRF-Chem 数值模拟

国家自然科学基金资助项目

52270097

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(1)
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