中国环境科学2024,Vol.44Issue(2) :699-707.

污泥热水解厌氧消化滤液处理工程溶解性有机物

Characteristics of dissolved organic matters in the treatment of the dewatering liquor of anaerobic digestion pretreated by thermal hydrolysis

岳文慧 刘吉宝 郭建宁 魏源送 隋倩雯
中国环境科学2024,Vol.44Issue(2) :699-707.

污泥热水解厌氧消化滤液处理工程溶解性有机物

Characteristics of dissolved organic matters in the treatment of the dewatering liquor of anaerobic digestion pretreated by thermal hydrolysis

岳文慧 1刘吉宝 2郭建宁 3魏源送 1隋倩雯2
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作者信息

  • 1. 中国科学院生态环境研究中心,环境模拟与污染控制国家重点联合实验室,北京 100085;中国科学院生态环境研究中心水污染控制实验室,北京 100085;中国科学院大学,北京 100049
  • 2. 中国科学院生态环境研究中心,环境模拟与污染控制国家重点联合实验室,北京 100085;中国科学院生态环境研究中心水污染控制实验室,北京 100085
  • 3. 深圳信息职业技术学院,广东深圳 518172
  • 折叠

摘要

以典型的污泥热水解厌氧消化滤液处理工程为对象进行现场调查.结果表明,滤液中氨氮和COD的浓度分别高达(2034±465),(4128±276)mg/L,滤液中溶解性有机物(DOM)主要是大分子难降解有机物,大于1000Da的DOM占80.6%.现有"生物预处理+两级AO-MBR"滤液处理工艺总体上可实现高效脱氮(TN去除率94.9%)和部分COD去除(69.9%).脱氮主要依赖生物预处理单元(去除贡献率为79.9%),而DOM去除主要依赖MBR工艺的膜过滤(去除贡献率为184.7%).膜过滤截留的DOM依次为高分子聚合物>腐植酸类物质>低分子有机酸和中性物质,出水DOM主要以腐植酸和富里酸类物质为主,且腐殖化程度增高.现有的水洗、酸洗和碱洗对膜的有机污染均有一定的清洗效果,但清洗液中DOM类型差异明显.

Abstract

An on-site investigation was conducted to characterize dissolved organic matter(DOM)in the anaerobic digestion(AD)filtrate that was generated from a typical sludge thermal hydrolysis process(THP).The results show that the concentrations of ammonia nitrogen and COD in the filtrate were as high as 2034(±465)and 4128(±276)mg/L,respectively,and the DOM concentration in the filtrate was mainly macromolecular refractory organic matter,and DOM>1000Da accounted for 80.6%.The existing"biological pretreatment+two-stage AO-MBR"filtrate treatment process could generally achieve a high-efficiency denitrification(TN removal rate of 94.9%and partial COD removal of 69.9%).Nitrogen removal relied mainly on biological pretreatment units(removal by 79.9%),while DOM removal on membrane filtration of the MBR process(removal by 184.7%).The membrane filtration intercepted DOM was in the order of high molecular polymer>humic acid substances>low molecular organic acids and neutral substances.The effluent DOM was mainly composed of humic acid and fulvic acid substances with a high degree of humification.Existing water washing,acid-and alkali washing had certain cleaning effects on organic pollution of membranes,but the types of DOM in the cleaning solution were significantly different.

关键词

污泥厌氧消化/溶解性有机物(DOM)/腐殖质/有机组分/三维荧光光谱

Key words

anaerobic sludge digestion/dissolved organic matter(DOM)/humics/organic component/3D-EEM

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基金项目

国家重点研发计划(2021YFC3200601)

中国科学院青年创新促进会项目(2021042)

出版年

2024
中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
参考文献量26
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