首页|用于沼气纯化的有机胺溶液吸收法研究进展

用于沼气纯化的有机胺溶液吸收法研究进展

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有机胺溶液吸收法作为一项成熟的碳捕集技术,具有CO2吸收速率快、选择性高及再生效果好等诸多优点,在沼气纯化领域具有重要的研究意义和应用价值,但也存在再生能耗高、易于挥发、易于降解和一些环境风险问题。不同类型的胺所表现出的沼气纯化效果不同,其中伯胺和仲胺的CO2吸收速率较快,但再生所需的能耗较大,叔胺和空间位阻胺的CO2吸收速率较慢,但再生能耗较低。本文从有机胺吸收法的工艺流程、反应机理、可操控变量、存在的问题及其应用现状等方面系统地回顾了有机胺吸收法在沼气纯化领域的研究进展,提出了相应的研究思路和建议,为继续推动有机胺吸收法在沼气纯化领域的应用提供指导。研究结果表明,适当提升有机胺的浓度可以明显提高CO2的吸收效率,且混合胺溶液有利于改善单胺溶液沼气纯化过程中经济性较低的问题。此外,相比于传统的干法吸收法,有机胺溶液吸收法在CO2捕集过程中的能耗会增加30%以上,这意味着有机胺溶液吸收法相对于干法吸收法需要更多的能源投入。
Research progresses on organic amine solution absorption method for biogas purification process
Organic amine solution absorption method,a mature carbon capture technology,has many advantages such as fast CO2 absorption rate,high selectivity and excellent regeneration effect,which has critical research significance and application value in the field of biogas upgrading,but has high regeneration energy consumption,volatility,degradability and some environmental risk issues which thus greatly restrict its commercial value.In this paper,the research progresses on organic amine absorption method in the field of biogas purification is systematically reviewed in terms of the process flow,reaction mechanism,manipulable variables,existing issues and its application status,and corresponding research ideas and suggestions are proposed to promote the application of organic amine absorption method in the field of biogas upgrading.The results show that the CO2 absorption efficiency can be significantly improved by appropriately elevating the concentration of amines,and the mixed amine solution can be conducive to the improvement of the lower economy in the biogas upgrading process of monoamine solution.In addition,compared to the traditional dry absorption method,the energy consumption of the amine solution absorption method in the CO2 capture process can be reduced by more than 30%,implying that the amine solution absorption method requires more energy input compared to the dry absorption method.

organic aminecarbon capturebiogas upgradingreaction mechanismregeneration energy consumption

孟凡志、韩思宇、林莉、李婧琳、陈凯轮、蒋建国

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清华大学环境学院,北京 100084

有机胺 碳捕集 沼气纯化 反应机理 再生能耗

国家自然科学基金

22176108

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(2)
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