中国环境科学2024,Vol.44Issue(3) :1244-1252.

改性赤泥负载Pt催化剂催化氧化甲苯的性能

Catalytic performance of Pt-supported modified red mud catalyst for toluene catalytic oxidation

方宏萍 梁文俊 马琛 马连刚 李桂贤
中国环境科学2024,Vol.44Issue(3) :1244-1252.

改性赤泥负载Pt催化剂催化氧化甲苯的性能

Catalytic performance of Pt-supported modified red mud catalyst for toluene catalytic oxidation

方宏萍 1梁文俊 2马琛 2马连刚 3李桂贤3
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作者信息

  • 1. 贵州理工学院资源与环境工程学院,贵州 贵阳 550003;北京工业大学环境与生命学部,区域大气复合污染防治北京市重点实验室,北京 100124
  • 2. 北京工业大学环境与生命学部,区域大气复合污染防治北京市重点实验室,北京 100124
  • 3. 贵州理工学院资源与环境工程学院,贵州 贵阳 550003
  • 折叠

摘要

以改性赤泥为载体,采用浸渍方法制备低成本改性赤泥(MRM)负载Pt催化剂,并探究Pt含量对Pt/MRM催化剂催化氧化甲苯活性影响.结果表明0.4Pt/MRM表现出最佳的催化活性,在 230℃时甲苯转化率为 100%.当空速高达 120000h-1时 0.4Pt/MRM催化剂依然能保持着较高的催化活性.当甲苯进口浓度为 5000mg/m3时仍可以有效氧化甲苯.采用XRD、FT-IR、BET、H2-TPR和O2-TPD等手段进行表征测试分析发现,MRM的比表面积较RM大幅度提高,使MRM能够更好分散活性组分Pt,成为合适的活性组分Pt的催化剂载体.同时所制备的xPt/MRM催化剂具有较高的比表面积和良好的孔结构.改性赤泥中Fe2O3与活性组分Pt物种相互作用,使催化剂的总氧解吸量增大,提高了催化剂表面氧的迁移率,从而提高了催化效率.

Abstract

A low-cost modified red mud supported Pt catalyst was prepared by impregnation method,and the effect of Pt content on catalytic oxidation activity of toluene on Pt/MRM catalyst was investigated.0.4Pt/MRM showed the best catalytic activity,and the toluene conversion rate reached 100%at 230℃.The catalytic activity of 0.4Pt/MRM was still higher when the airspeed was up to 120000h-1.Toluene can be oxidized effectively in a wide range of toluene concentrations.XRD,FT-IR,BET,H2-TPR and O2-TPD were used to characterize.The specific surface area of MRM was significantly higher than RM,which can disperse the active component Pt better and become a suitable catalyst carrier for the active component Pt.The prepared xPt/MRM catalyst had high surface area and good pore structure.The interaction between Fe2O3 and Pt species in the modified red mud increased the total oxygen desorption capacity of the catalyst,improved the mobility of oxygen on the catalyst surface,and the catalytic efficiency.

关键词

改性赤泥/Pt/催化燃烧/甲苯

Key words

modified red med/Pt/catalytic combustion/toluene

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基金项目

国家环境保护恶臭污染控制重点实验室开发基金资助项目(20210504)

贵州理工学院高层次人才科研启动项目(XJGC20190635)

贵州省教育厅高等学校人文社会科学研究基地项目(23RWJD07)

国家自然科学基金资助项目(22378008)

出版年

2024
中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
参考文献量42
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