中国环境科学2024,Vol.44Issue(3) :1526-1533.

磁性浮珠VMB@Fe3O4@CS对鱼腥藻和微囊藻的去除

Effect and mechanism of magnetic floatable bead VMB@Fe3O4@CS on removing Anabaena and Microcystis

车文露 赵岩 张高山 李彦鹏
中国环境科学2024,Vol.44Issue(3) :1526-1533.

磁性浮珠VMB@Fe3O4@CS对鱼腥藻和微囊藻的去除

Effect and mechanism of magnetic floatable bead VMB@Fe3O4@CS on removing Anabaena and Microcystis

车文露 1赵岩 1张高山 1李彦鹏2
扫码查看

作者信息

  • 1. 长安大学水利与环境学院,陕西 西安 710054
  • 2. 长安大学水利与环境学院,陕西 西安 710054;长安大学旱区地下水文与生态效应教育部重点实验室,陕西 西安 710054
  • 折叠

摘要

为了有效处理有害藻华,并避免化学物质二次污染,结合磁絮凝与浮珠浮选方法,以玻化微珠、Fe3O4、壳聚糖为原料合成磁浮珠VMB@Fe3O4@CS,对水华鱼腥藻和铜绿微囊藻进行去除实验.结果表明,磁浮珠对2种水华藻的最佳去除效率分别达到99.01%(0.12g/L)、98.6%(0.21g/L).VMB@Fe3O4@CS在较宽的pH值范围(4~10)和水温范围(5℃~35℃)内实现较高的去除率(>60%),离子强度的增加对微藻的去除起负面影响.通过形态学观察、表面疏水率及Zeta电位分析确定静电吸引、吸附架桥是磁浮珠对藻细胞主要的絮凝机理.制备的VMB@Fe3O4@CS去除有害藻华具有很大应用潜力.

Abstract

In order to effectively treat harmful algal blooms and avoid secondary pollution by chemical substances,maglev beads VMB@Fe3O4@CS were synthesized through a novel method combined with magnetic flocculation and float flotation which use vitrified microbeads,Fe3O4 and chitosan as raw materials,to remove Anabaena flos-aquae and Microcystis aeruginosa.The results showed that the optimal removal efficiencies of the two species of algae were 99.01%(0.12g/L)and 98.6%(0.21g/L),respectively.VMB@Fe3O4@CS achieved a high removal rate(>60%)in a wide pH range(4~10)and water temperature range(5~35℃),and the increase of ionic strength had a negative effect on the removal of microalgae.Through morphological observation,surface hydrophobicity and Zeta potential analysis,it was determined that electrostatic attraction and adsorption bridging were the main flocculation mechanisms of maglev beads on algal cells.The experimental results show that the prepared VMB@Fe3O4@CS has a great potential to control harmful algal blooms.

关键词

有害藻华/磁性浮珠浮选/絮凝

Key words

harmful algal blooms/magnetic buoyant-bead flotation/flocculation

引用本文复制引用

基金项目

陕西省自然科学基金资助项目(2020JM-236)

出版年

2024
中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
参考文献量37
段落导航相关论文