中国环境科学2024,Vol.44Issue(5) :2652-2659.

CO2对A.ferrooxidans活性和次生铁矿物形成的影响

Effect of CO2 on the activity and formation of secondary iron minerals by Acidithiobacillus ferrooxidans

黄海涛 耿康慧 伍贤辉 王崇 魏彩春
中国环境科学2024,Vol.44Issue(5) :2652-2659.

CO2对A.ferrooxidans活性和次生铁矿物形成的影响

Effect of CO2 on the activity and formation of secondary iron minerals by Acidithiobacillus ferrooxidans

黄海涛 1耿康慧 2伍贤辉 2王崇 2魏彩春1
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作者信息

  • 1. 桂林理工大学,环境科学与工程学院,广西桂林 541004;桂林理工大学,广西环境污染控制理论与技术重点实验室,岩溶地区水污染控制与用水安全保障协同创新中心,广西桂林 541004
  • 2. 桂林理工大学,环境科学与工程学院,广西桂林 541004;桂林理工大学生态环保现代产业学院,广西桂林 541004
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摘要

通过摇瓶试验模拟富铁富硫酸盐环境,研究了在0.03%(空气中 CO2含量),3%,6%,9%和 12%浓度的CO2条件下对Acidithiobacillus ferrooxidans活性及次生铁矿物形成的影响,并分析了 pH值,Fe2+氧化率及氧化速率,总Fe沉淀率以及次生铁矿物矿相等相关指标.结果表明,CO2浓度为3%时,菌氧化Fe2+能力最强,72h时Fe2+氧化率达到100%,试验结束时总Fe沉淀率最高,为42.8%.随着CO2浓度增加,各体系A.ferrooxidans活性受到抑制.不同CO2浓度体系最终获得矿物均为黄铁矾类矿物混合少量施氏矿物.适当提高CO2浓度,有助于提高A.ferrooxidans活性,并促进水解成矿增加矿物产量.本研究为酸性矿山废水的治理提供理论依据.

Abstract

The effects of 0.03%(CO2 content in air),3%,6%,9%and 12%CO2 concentrations on the activity of Acidithiobacillus ferrooxidans and the formation of secondary iron minerals were studied using shaking flask experiments to simulate the iron-rich and sulfate-rich environment.The pH,Fe2+oxidation rate and oxidation rate,total Fe precipitation rate and secondary iron mineral phase-related indicators were analysed.The results showed that when the concentration of CO2 was 3%,the ability of bacteria to oxidise Fe2+was the strongest and the oxidation efficiency of Fe2+reached 100%at 72h.At the end of the experiment,the total Fe precipitation rate was the highest,at 42.8%.With the increase in CO2 concentration,the activity of A.ferrooxidans in each system was inhibited.The final minerals obtained in different CO2 concentration systems were all jarosite minerals mixed with a small amount of schwertmannite.An appropriate increase in CO2 concentration is therefore helpful to improve the activity of A.ferrooxidans and promote hydrolysis mineralisation,thus increasing mineral yield.This study provides a theoretical basis for the treatment of acid mine waste water.

关键词

CO2/嗜酸性氧化亚铁硫杆菌/生物氧化/次生铁矿物

Key words

CO2/A.ferrooxidans/biooxidation/secondary iron minerals

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基金项目

广西环境污染控制理论与技术重点实验室科教结合科技创新基地项目()

广西环境污染控制理论与技术重点实验室研究项目(1601Z005)

桂林理工大学科研启动基金(GUTQDJJ 2005020)

出版年

2024
中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCSCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
参考文献量36
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