首页|基于OLI和TROPOMI卫星数据的北京市臭氧前体物研究

基于OLI和TROPOMI卫星数据的北京市臭氧前体物研究

扫码查看
甲醛(HCHO)和二氧化氮(NO2)是重要的臭氧前体物,其比值(FNR)可用于指示臭氧生成敏感性,是臭氧污染防控的主要参考。本研究基于过采样算法提高TROPOMI HCHO和NO2空间分辨率并降低原始数据的不确定性,揭示北京市 2021 年夏季HCHO和NO2空间分布特征,基于FNR诊断北京地区臭氧生成敏感性。根据Landsat8 OLI数据计算北京地区环境指数及不透水面占比,并分析与HCHO、NO2及FNR的关系,揭示北京城市化程度与O3、VOCs和NOx排放的关系。研究发现,北京市NO2高值主要分布在城市中心区域,非城区NO2柱浓度显著减少。NO2柱浓度均值随着不透水面占比的升高明显增大,但标准差逐渐变小,表明随着北京主城区城市化程度越来越高,城区内部NO2排放差异越来越小。北京市城市中心区域HCHO柱浓度总体上高于非城区,但由于植被排放的异戊二烯的贡献从一定程度上弱化了城市化程度差异造成的VOCs排放差距。北京市主城区及东部廊坊一带的O3 表现为受VOCs控制,而北京市北部郊区的O3主要受NOx控制。FNR均值随着不透水面占比的升高,明显减小,表明随着北京地区城市化程度的提高,臭氧生成敏感性逐渐向VOCs控制机制转变。
Study on ozone precursors in Beijing based on OLI and TROPOMI satellite data
Formaldehyde(HCHO)and nitrogen dioxide(NO2)are important precursors to ozone.HCHO to NO2 ratio(FNR)indicates the sensitivity of ozone production,serving as a primary reference for ozone pollution control.This study enhances the spatial resolution of TROPOMI HCHO and NO2 columns by oversampling algorithms,and reduces the uncertainty of TROPOMI data.It reveals the spatial distribution characteristics of HCHO and NO2 in Beijing during the summer of 2021.Based on FNR,the study diagnoses the sensitivity of ozone production in the Beijing areas.The study utilizes Landsat 8OLI data to calculate environmental indices and the proportion of impervious surfaces in the Beijing areas,and analyses their relationships with HCHO,NO2,and FNR.This Study aims to reveal the relationship between the degree of urbanization and the emissions of O3,VOCs,and NOx in Beijing.It finds that high NO2 columns are mainly distributed in the center of Beijing urban areas,with significantly reduced NO2 columns in non-urban areas.The mean NO2 columns increases with the proportion of impervious surfaces,but their standard deviation decreases,indicating that as urbanization in the urban areas of Beijing intensifies,the differences in NO2 emissions within urban areas diminish.The HCHO columns in urban Beijing are generally higher than those in non-urban areas,but the contribution of isoprene emissions from vegetation somewhat mitigates the disparity in VOCs emissions caused by the urbanization degree differences.Ozone in the urban area of Beijing and eastern Langfang area is controlled by VOCs,while ozone in the northern suburbs of Beijing is primarily controlled by NOx.The FNR mean decreases with an increase in the proportion of impervious surfaces,indicating that as urbanization in the Beijing area advances,the sensitivity of ozone production gradually shifts to a VOCs-controlled mechanism.

TROPOMILandsat 8 OLIHCHOVOCsNOx

蒲东川、王大康、朱雷、杨现坤、王晋年

展开 >

哈尔滨工业大学环境学院,黑龙江 哈尔滨 150090

南方科技大学环境科学与工程学院,广东 深圳 518055

广州大学地理科学与遥感学院,广东 广州 510006

TROPOMI Landsat 8 OLI 甲醛 VOCs 二氧化氮

国家自然科学基金资助项目国家重点研发项目

423750902021YFE0117300

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(7)
  • 40