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长三角地区南京市表土重金属污染特征及源解析

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以南京市主城区浅表层土壤为例,分析长三角地区典型工业城市土壤重金属Cd、Cr、Cu、Mn、Ni、Pb和Zn的污染特征,并用克里金法与多元统计分析法,解析土壤重金属来源。结果表明:南京市主城区土壤中Cd、Cr、Cu、Mn、Ni、Pb和Zn均存在富集现象,含量均值分别为0。24、76。9、36。45、707。22、35。48、32。65 和 99。75mg/kg。从空间分布特征来看,南京市土壤重金属元素Zn、Cu、Cd和Pb在工业区含量较高,Zn、Cu及Pb在老城区存在高值;Ni、Cr在工业区含量普遍较高,在老城区含量整体较低;Mn分布趋势较平缓,且与其他 6 种重金属元素分布特征明显不同。结合主成分分析与聚类分析结果可知,南京市土壤中Zn、Cu、Cd、Pb主要受工业和交通活动的影响,Ni和Cr主要受工业活动影响,Mn主要为自然来源。工业与交通活动是造成长三角地区工业城市土壤重金属污染的重要原因,同时也是长三角地区土壤重金属污染治理的重要方向。
Characterization and source analysis of topsoil heavy metal pollution in Nanjing,Yangtze River Delta Region
This study examined the pollution characteristics of heavy metals(Cd,Cr,Cu,Mn,Ni,Pb,and Zn)in the shallow soils of Nanjing's urban core,a typical industrial city in the Yangtze River Delta.The sources of heavy metals in the soil were interpreted using kriging and multivariate statistical analysis methods.The results showed that Cd,Cr,Cu,Mn,Ni,Pb,and Zn were all enriched in the soil of the main urban area of Nanjing,with average contents of 0.24,76.9,36.45,707.22,35.48,32.65,and 99.75mg/kg,respectively.From the perspective of spatial distribution characteristics,it was found that the contents of heavy metal elements Zn,Cu,Cd,and Pb in the soil of Nanjing were higher in industrial areas.High values of Zn,Cu,and Pb were observed in the old urban areas.The contents of Ni and Cr were generally higher in industrial areas and lower in the old urban areas.The distribution trend of Mn was relatively gentle and significantly different from the other six heavy metal elements.Based on the results of principal component analysis and cluster analysis,it could be determined that Zn,Cu,Cd,and Pb in the soil of Nanjing were mainly affected by industrial and transportation activities.Ni and Cr were primarily influenced by industrial activities,while Mn was mainly from natural sources.Industrial and transportation activities were identified as important causes of heavy metal pollution in the soil of industrial cities in the Yangtze River Delta region.They were also crucial directions for the prevention and control of soil heavy metal pollution in the Yangtze River Delta region.

urban topsoilsoil heavy metalspatial distributionsources analysisYangtze River DeltaNanjing

杨昱莹、刘亮、陈明、赖涓涓、王彦瑜、郝燕芳

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南京林业大学林学院,南方现代林业协同创新中心,江苏省水土保持与生态修复重点实验室,江苏 南京 210037

福建水利电力职业技术学院,福建 永安 366000

城市表土 土壤重金属 空间分布 物源解析 长三角地区 南京市

国家自然科学基金资助项目

42277352

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(7)
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