首页|场地土壤镉污染排放清单与溯源——以铜冶炼厂为例

场地土壤镉污染排放清单与溯源——以铜冶炼厂为例

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以华东地区某铜冶炼厂为例,采用"四大排放途径"函数定量描述Cd通过"废气沉降、废水排放、固废淋滤、跑冒滴漏"进入土壤的通量。结合AERMOD废气沉降模型,计算废气携带的Cd沉降于场地边界内部和外部的分布,明确各途径对场地内土壤Cd污染的贡献。结果表明,企业在2000~2002年在产期间主要通过废气(1411kg,50。05%)和固废淋滤(1327kg,47。05%)排放Cd,而废水及跑冒滴漏途径影响很小(共81。74kg,2。90%)。但所排废气中的Cd沉降于场地内的仅0。68kg(0。05%),场地内土壤Cd主要由固废淋滤途径贡献。空间排放清单显示其主要分布于堆料区和废气处理区等生产区域。研究结果对加强冶炼行业的精细化源头管控有重要指导作用,且本文提出的方法可拓展至其他行业和多种污染物的排放量溯源。
Constructing soil cadmium discharge inventory for source analysis——a case study in copper smelter
This study took a copper smelting plant in East China as an example,and used the"four emission pathways"functions to quantitatively describe the flux of Cd entering soil through"waste gas deposition,wastewater discharge,solid waste leaching,and run-off and leakage".Combining the waste gas deposition model(AERMOD),the distribution of Cd carried by waste gas was calculated inside and outside the site boundary,and the contribution of each pathway to soil Cd pollution in the site was clarified.The results indicated that during the production period from 2000 to 2002,Cd was mainly emitted through waste gas deposition(1411kg,50.05%)and solid waste leaching(1327kg,47.05%),while the impact of wastewater and run-off as well as leakage pathways was small(a total of 81.74kg,2.90%).However,only 0.68kg Cd in the waste gas was deposited inside the site,which only account for 0.05%of the overall Cd pollution in the soil of this site,while soil Cd in the site was mainly contributed by the solid waste leaching pathway.The spatial discharge inventory showed that soil Cd pollution was mainly distributed in production areas such as the stacking area and waste gas treatment area.The research results have important significance for strengthening the fine source control of the smelting industry,and the method proposed in this article can be extended to the source analysis of other industries and multiple pollutants.

soil cadmium pollutionwaste gas deposition modelsolid waste leachingspatial discharge inventorysource management and control

盛溢、薛玮真、应迪文、吴骏、李晔、史沛丽、赵玲

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浙江工业大学化学工程学院,浙江杭州 310014

上海交通大学环境科学与工程学院,上海 200240

华东师范大学地理信息科学教育部重点实验室,上海 200241

生态环境部土壤与农业农村生态环境监管技术中心,北京 100012

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土壤镉污染 废气沉降模型 固废淋滤 空间排放清单 源头管控

国家重点研发计划土壤专项

2020YFC1806700

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(8)