首页|DN-PN/A耦合处理低氨氮电镀尾水研究

DN-PN/A耦合处理低氨氮电镀尾水研究

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以物化预处理后的电镀工业园区尾水为处理对象,构建了中试规模连续流形式的反硝化-部分亚硝化-厌氧氨氧化多单元反应器,前置反硝化TIN和COD的去除率为(29.96±10.37)和(73.33±9.6)%,大量溶解性有机物被去除,减少了污染物对后续单元的冲击.亚硝化单元验证了沸石填料的方法有助于实现稳定亚硝化,NAR达到(87.73±22.28)%,长期运行过程中会受水垢影响,水垢清除后性能可恢复.厌氧氨氧化单元为主要脱氮单元,在亚硝化单元失衡情况,依靠AOB与DNB和AnAOB协同作用,能够贡献TIN去除(41.25±14.46)%.微生物高通量测序结果表明,亚硝化反应器检出AOB功能菌Nitrosomonas,相对丰度为5.45%,Anammox功能菌Candidatus Anammoxoglobus,其相对丰度达到25.91%.本文为厌氧氨氧化工艺工程化应用提供理论与实践基础.
Research on DN-PN/A coupled treatment of low ammonia nitrogen electroplating tail water
A pilot-scale continuous-flow denitrification partial nitrification-anaerobic ammonia oxidation(Anammox)multi-unit reactor was constructed to treat the electroplating tail wastewater.The pre-denitrification reactor demonstrated total inorganic nitrogen(TIN)and chemical oxygen demand(COD)removal efficiencies of(29.96±10.37)%and(73.33±9.6)%,respectively,with substantial removal of soluble organics to reduce pollutant loads in subsequent processes.The partial nitrification reactor confirmed that the zeolite packing method effectively achieved stable partial nitrification,yielding a nitrogen accumulation rate of(87.73±22.28)%.During long-term operation,it will be affected by scale,and its performance can be restored after scale removal.The Anammox reactor,as the primary nitrogen removal stage,maintained a TIN removal efficiency of(41.25±14.46)%even during partial nitrification instability,relying on the cooperative effects of ammonia-oxidizing bacterium(AOB),denitrifying bacteria(DNB),and anammox bacteria(AnAOB).High-throughput sequencing identified Nitrosomonas(AOB),in the partial nitrification reactor,with a relative abundance of 5.45%,and Candidatus Anammoglobus(AnAOB),with a relative abundance of 25.91%.These findings provide both theoretical and practical foundations for applying the Anammox process in engineering contexts.

anammoxlow ammonia nitrogen electroplating tail wastewaterhigh efficiency nitrogen removalpartial nitrificationzeolite

章裕、李嘉懿、杨俊锋、周松伟、汪晓军

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华南理工大学环境与能源学院,广东 广州 510006

佛山市化尔铵生物科技有限公司,广东 佛山 528300

厌氧氨氧化 电镀低氨氮尾水 高效脱氮 亚硝化 沸石

2024

中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
年,卷(期):2024.44(12)