中国环境科学2024,Vol.44Issue(12) :6651-6657.

DN-PN/A耦合处理低氨氮电镀尾水研究

Research on DN-PN/A coupled treatment of low ammonia nitrogen electroplating tail water

章裕 李嘉懿 杨俊锋 周松伟 汪晓军
中国环境科学2024,Vol.44Issue(12) :6651-6657.

DN-PN/A耦合处理低氨氮电镀尾水研究

Research on DN-PN/A coupled treatment of low ammonia nitrogen electroplating tail water

章裕 1李嘉懿 1杨俊锋 1周松伟 2汪晓军1
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作者信息

  • 1. 华南理工大学环境与能源学院,广东 广州 510006
  • 2. 佛山市化尔铵生物科技有限公司,广东 佛山 528300
  • 折叠

摘要

以物化预处理后的电镀工业园区尾水为处理对象,构建了中试规模连续流形式的反硝化-部分亚硝化-厌氧氨氧化多单元反应器,前置反硝化TIN和COD的去除率为(29.96±10.37)和(73.33±9.6)%,大量溶解性有机物被去除,减少了污染物对后续单元的冲击.亚硝化单元验证了沸石填料的方法有助于实现稳定亚硝化,NAR达到(87.73±22.28)%,长期运行过程中会受水垢影响,水垢清除后性能可恢复.厌氧氨氧化单元为主要脱氮单元,在亚硝化单元失衡情况,依靠AOB与DNB和AnAOB协同作用,能够贡献TIN去除(41.25±14.46)%.微生物高通量测序结果表明,亚硝化反应器检出AOB功能菌Nitrosomonas,相对丰度为5.45%,Anammox功能菌Candidatus Anammoxoglobus,其相对丰度达到25.91%.本文为厌氧氨氧化工艺工程化应用提供理论与实践基础.

Abstract

A pilot-scale continuous-flow denitrification partial nitrification-anaerobic ammonia oxidation(Anammox)multi-unit reactor was constructed to treat the electroplating tail wastewater.The pre-denitrification reactor demonstrated total inorganic nitrogen(TIN)and chemical oxygen demand(COD)removal efficiencies of(29.96±10.37)%and(73.33±9.6)%,respectively,with substantial removal of soluble organics to reduce pollutant loads in subsequent processes.The partial nitrification reactor confirmed that the zeolite packing method effectively achieved stable partial nitrification,yielding a nitrogen accumulation rate of(87.73±22.28)%.During long-term operation,it will be affected by scale,and its performance can be restored after scale removal.The Anammox reactor,as the primary nitrogen removal stage,maintained a TIN removal efficiency of(41.25±14.46)%even during partial nitrification instability,relying on the cooperative effects of ammonia-oxidizing bacterium(AOB),denitrifying bacteria(DNB),and anammox bacteria(AnAOB).High-throughput sequencing identified Nitrosomonas(AOB),in the partial nitrification reactor,with a relative abundance of 5.45%,and Candidatus Anammoglobus(AnAOB),with a relative abundance of 25.91%.These findings provide both theoretical and practical foundations for applying the Anammox process in engineering contexts.

关键词

厌氧氨氧化/电镀低氨氮尾水/高效脱氮/亚硝化/沸石

Key words

anammox/low ammonia nitrogen electroplating tail wastewater/high efficiency nitrogen removal/partial nitrification/zeolite

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出版年

2024
中国环境科学
中国环境科学学会

中国环境科学

CSTPCDCSCDCHSSCD北大核心
影响因子:2.174
ISSN:1000-6923
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