首页|The Novel Benzo-15-Crown-5 with Palladium(II) Complex:[Na(B15C5)]2[Pd(SCN)4]

The Novel Benzo-15-Crown-5 with Palladium(II) Complex:[Na(B15C5)]2[Pd(SCN)4]

扫码查看
原文链接
  • NETL
  • NSTL
  • 万方数据
A novel Pd(II) Benzo-15-crown-5 complex [Na(B15C5)]2[Pd(SCN)4] has been isolated and characterized by IR and X-ray diffraction analysis.The crystal structure belongs to monoclinic,space group P21/n with cell dimensions,a=1.0164(6),b=1.3743(3),c=1.4987(7) nm,b=95.248(6)o ,V=2.0847nm3,Z=2,F(000)=944,R=0.053,Rw=0.072.The compound consists of two [Na(B15C5)]+ complex cations and a [Pd(SCN)4]2- complex anion.Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)4]2- to form stable neutral complex.

Benzo-15-crown-5,crown ether,crystal structure,palladium complex

Lan Ying ZHU、Jian Min DOU、Ying LIU、De Zhi SUN、Pei Ju ZHENG、Chen Xia DU、Yu ZHU

展开 >

Department of Biology and Chemistry,Liaocheng Teacher's University,Liaocheng 252000

Research Center of Analysis and Measurement,Fudan University,Shanghai 200433

Key Laboratory of Applied Chemistry,Zhengzhou University,Zhengzhou 450052

2000

中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCDSCI
影响因子：0.771
ISSN：1001-8417
年,卷(期)：2000.11(9)
  • 6
  • 11