首页|Recent advances in two-step energy transfer light-harvesting systems driven by non-covalent self-assembly
Recent advances in two-step energy transfer light-harvesting systems driven by non-covalent self-assembly
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Sequential energy transfer is ubiquitous in natural light-harvesting systems(LHSs),which greatly pro-motes the exploitation of light energy.The LHSs in nature are sophisticated supramolecular assemblies of chlorophyll molecules that carry out efficient light harvesting through cascade energy transfer process.Inspired by nature,scientists have paid much attention to fabricate stepwise LHSs based on assorted supramolecular scaffolds in recent years.Light-harvesting antennas and energy acceptors can be accom-modated in particular scaffolds,which offer great convenience for energy transfer between them.These systems not only further mimic photosynthesis,but also demonstrate many potential applications,such as photocatalysis,tunable luminescence,and information encryption,etc.In this review article,aiming at of-fering a practical guide to this emerging research field,the introduction of construction strategies towards sequential LHSs will be presented.Different scaffolds are classified and highlighted,including host-guest assemblies,metal-coordination assemblies,as well as bio-macromolecular and other supramolecular scaf-folds.
Light-harvesting systemSupramolecular self-assemblySequential energy transferTunable fluorescenceFRET
Zhiying Wu、Hongwei Qian、Xiuxiu Li、Tangxin Xiao、Leyong Wang
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Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology,School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
Key Laboratory of Mesoscopic Chemistry of MOE,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210023,China