首页|From oxygenated monomers to well-defined low-carbon polymers

From oxygenated monomers to well-defined low-carbon polymers

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The synthesis of degradable polymers with easy-to-break in-chain carbon-oxygen bonds has attracted much attention.This minireview introduces the synthesis of a variety of degradable polymers from the(co)polymerizations of several typical oxygenated monomers such as epoxides,cyclic carbonates,cyclic esters,carbon dioxide(CO2),carbonyl sulfide(COS),and cyclic anhydrides.We highlight the catalysts and mechanisms for these(co)polymerizations.The ring-opening copolymerization of five-membered carbon-ate with cyclic anhydride or COS has been introduced.We also highlight the synthesis of block copoly-mers and cyclic copolymers with well-defined sequences by the method of growing center switching.We hope that these new polymerization systems can provide new ideas for the development of degradable low-carbon polymers in the future.

Polymer synthesisDegradable polymerLow-carbon polymerCatalysisRing-opening polymerization

Yanni Xia、Chengjian Zhang、Yong Wang、Shunjie Liu、Xinghong Zhang

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National Key Laboratory of Biobased Transportation Fuel Technology,International Research Center for X Polymers,Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310027,China

School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China

Key Laboratory of Polymer Ecomaterial,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China

Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering,Hangzhou 310027,China

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国家自然科学基金国家自然科学基金浙江省科技厅项目

52203129519731902020R52006

2024

10.1016/j.cclet.2023.108860

中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCD
影响因子：0.771
ISSN：1001-8417
年,卷(期)：2024.35(1)
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