From oxygenated monomers to well-defined low-carbon polymers

Yanni Xia ¹Chengjian Zhang ¹Yong Wang ²Shunjie Liu ³Xinghong Zhang⁴

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作者信息

1. National Key Laboratory of Biobased Transportation Fuel Technology,International Research Center for X Polymers,Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310027,China
2. School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China
3. Key Laboratory of Polymer Ecomaterial,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
4. National Key Laboratory of Biobased Transportation Fuel Technology,International Research Center for X Polymers,Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310027,China;Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering,Hangzhou 310027,China
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Abstract

The synthesis of degradable polymers with easy-to-break in-chain carbon-oxygen bonds has attracted much attention.This minireview introduces the synthesis of a variety of degradable polymers from the(co)polymerizations of several typical oxygenated monomers such as epoxides,cyclic carbonates,cyclic esters,carbon dioxide(CO2),carbonyl sulfide(COS),and cyclic anhydrides.We highlight the catalysts and mechanisms for these(co)polymerizations.The ring-opening copolymerization of five-membered carbon-ate with cyclic anhydride or COS has been introduced.We also highlight the synthesis of block copoly-mers and cyclic copolymers with well-defined sequences by the method of growing center switching.We hope that these new polymerization systems can provide new ideas for the development of degradable low-carbon polymers in the future.

Key words

Polymer synthesis/Degradable polymer/Low-carbon polymer/Catalysis/Ring-opening polymerization

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基金项目

国家自然科学基金(52203129)

国家自然科学基金(51973190)

浙江省科技厅项目(2020R52006)

出版年

2024

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCD

影响因子：0.771

ISSN：1001-8417

参考文献量2

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