Abstract
The rapid and precise fabrication of multiscale supramolecular assemblies using micro/nanofluidic tech-niques has emerged as a dynamic area of research in supramolecular chemistry,materials chemistry,and organic chemistry.This review summarizes the application of micro/nanofluidic techniques in con-structing supramolecular assemblies,including nanoscale supramolecular assemblies such as macrocycles and cages,microscale supramolecular assemblies such as metal organic frameworks(MOFs)and covalent organic frameworks(COFs),and macroscale supramolecular assemblies such as supramolecular hydro-gels.Compared to conventional synthesis methods,micro/nanofluidic techniques for the production of supramolecular assemblies have significant advantages,including enhanced safety,high reaction rates,improved selectivity/yield,and scalability.Additionally,micro/nanofluidic systems facilitate the creation of precisely controllable micro/nanoconfined environments,allowing for a unique flow behavior that im-proves our understanding of the supramolecular self-assembly process.Such systems may also lead to the development of novel supramolecular assemblies that differ from those generated via traditional meth-ods.
基金项目
国家自然科学基金(22107028)
国家自然科学基金(22103062)
Program of Shanghai Outstanding Academic Leaders(21XD1421200)
上海市科委项目(22JC1403900)
NETL
NSTL
万方数据