首页|Eco-friendly iron-catalyzed oxidation of unstrained tertiary aromatic alcohols to ketones
Eco-friendly iron-catalyzed oxidation of unstrained tertiary aromatic alcohols to ketones
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A general,facile and eco-friendly iron catalysis enables oxidation of unstrained tertiary aromatic alcohols to ketones through C-C bond cleavage even with H2O2 as the oxidant.Notably,this transformation can tolerate oxidation-labile functional groups.The robustness of this method is further demonstrated on the late-stage oxidation of complex bioactive molecules.
Iron catalysisC-C bond cleavageOxidationH2O2Late-stage functionalization
Shanmei Zhu、Penghui Hu、Mengying Guo、Linlin Zhao、Linlin Yang、Wei-Jin Gu、Wei Han
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Jiangsu Collaborative Innovation Center of Biomedical Functional Materials,Jiangsu Key Laboratory of Biofunctional Materials,Key Laboratory of Applied Photochemistry,School of Chemistry and Materials Science,Nanjing Normal University,Nanjing 210023,China
国家自然科学基金the"Qing Lan Project"Young and Middleaged Academic Leaders of Jiangsu Provincial Colleges and Universities江苏高校优势学科建设工程项目
NETL
NSTL
万方数据
维普
