Abstract
A general,facile and eco-friendly iron catalysis enables oxidation of unstrained tertiary aromatic alcohols to ketones through C-C bond cleavage even with H2O2 as the oxidant.Notably,this transformation can tolerate oxidation-labile functional groups.The robustness of this method is further demonstrated on the late-stage oxidation of complex bioactive molecules.
基金项目
国家自然科学基金(21776139)
the"Qing Lan Project"Young and Middleaged Academic Leaders of Jiangsu Provincial Colleges and Universities()
江苏高校优势学科建设工程项目()
NETL
NSTL
维普
万方数据