中国化学快报(英文版)2024,Vol.35Issue(1) :456-460.DOI:10.1016/j.cclet.2023.108494

A shape-reconfigurable,light and magnetic dual-responsive shape-memory micropillar array chip for droplet manipulation

Wen-Qi Ye Wen-Xin Fu Xiao-Peng Liu Chun-Guang Yang Zhang-Run Xu
中国化学快报(英文版)2024,Vol.35Issue(1) :456-460.DOI:10.1016/j.cclet.2023.108494

A shape-reconfigurable,light and magnetic dual-responsive shape-memory micropillar array chip for droplet manipulation

Wen-Qi Ye 1Wen-Xin Fu 1Xiao-Peng Liu 1Chun-Guang Yang 1Zhang-Run Xu1
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作者信息

  • 1. Research Center for Analytical Sciences,Northeastern University,Shenyang 110819,China
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Abstract

Droplet manipulation on an open surface has great potential in chemical analysis and biomedicine engi-neering.However,most of the reported platforms designed for the manipulation of water droplets cannot thoroughly solve the problem of droplet evaporation.Herein,we report a shape-reconfigurable micropil-lar array chip for the manipulation of water droplets,oil droplets and water-in-oil droplets.Water-in-oil droplets provide an enclosed space for water droplets,preventing the evaporation in an open environ-ment.Perfluoropolyether coated on the surface of the chip effectively reduces the droplet movement resistance.The micropillar array chip has light and magnetic dual-response due to the Fe3O4 nanoparti-cles and the reduced iron powder mixed in the shape-memory polymer.The micropillars irradiated by a near-infrared laser bend under the magnetic force,while the unirradiated micropillars still keep their original shape.In the absence of a magnetic field,when the micropillars in a temporary shape are irradi-ated by the near-infrared laser to the transition temperature,the micropillars return to their initial shape.In this process,the surface morphology gradient caused by the deformation of the micropillars and the surface tension gradient caused by the temperature change jointly produce the driving force of droplet movement.

Key words

Microfluidics/Droplet manipulation/Micropillar array/Shape memory polymer/Magnetic response/Light response

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基金项目

国家自然科学基金(21874015)

中央高校基本科研业务费专项(N2005024)

出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCDCSCD
影响因子:0.771
ISSN:1001-8417
参考文献量29
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