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Recent advances in visible light-mediated chemical transformations of enaminones
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Enaminones,which possesses both the nucleophilic enamine as well as electrophilic enone structures,are well known versatile building blocks in organic synthesis.Meanwhile,visible light-mediated reac-tions have emerged as useful synthetic strategy with enhanced sustainability.Around the last decade,various photochemical transformations of enaminones have been developed to construct cyclic or acyclic compounds.In this review,we describe the recent advances in visible light-mediated chemical transfor-mations of enaminones.Detailed discussion on the reaction mechanism of the related reactions is given to provide guide to the reader.Finally,a summary on the existing challenges and the future outlook towards the development of practical photocatalytic reactions of enaminones is also presented.
EnaminoneVisible lightC-H functionalizationC=C bond cleavageCyclizationMulticomponent reactions
Yu Han、Liyun Zhou、Chengyu Wang、Shangti Feng、Rong Ma、Jie-Ping Wan
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College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330022,China
School of Chemistry and Chemical Engineering,Linyi University,Linyi 276000,China
Linyi Sanfeng Chemical Co.,Ltd.,Linyi 276000,China
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