中国化学快报(英文版)2024,Vol.35Issue(2) :411-414.DOI:10.1016/j.cclet.2023.108979

Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides

Sen Qiao Kunquan Chen Qiang Liu Zhixiang Wang Xiangyu Chen
中国化学快报(英文版)2024,Vol.35Issue(2) :411-414.DOI:10.1016/j.cclet.2023.108979

Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides

Sen Qiao 1Kunquan Chen 1Qiang Liu 1Zhixiang Wang 2Xiangyu Chen2
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作者信息

  • 1. School of Chemical Sciences,University of the Chinese Academy of Sciences,Beijing 100049,China
  • 2. School of Chemical Sciences,University of the Chinese Academy of Sciences,Beijing 100049,China;Binzhou Institute of Technology,Weiqiao-UCAS Science and Technology Park,Binzhou 256606,China
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Abstract

A charge transfer complex(CTC)-enabled photoreduction of ether phosphonium salts for the generation of oxyalkyl radicals was described.The photoreduction provides a convenient method to achieve selective oxyalkylation of enamides with broad substrate scope.The method features operational simplicity,mild and inherent green conditions.

Key words

Enamides/Phosphonium salts/Ethers/Charge transfer complex/Visible light

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基金项目

国家自然科学基金(22001248)

Fundamental Research Funds for the Central Universities and University of Chinese Academy of Sciences()

出版年

2024
中国化学快报(英文版)
中国化学会

中国化学快报(英文版)

CSTPCDCSCD
影响因子:0.771
ISSN:1001-8417
参考文献量63
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