Deactivation mechanisms and anti-deactivation strategies of molecular sieve catalysts for NOx reduction

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外文摘要：Molecular sieve catalysts,owing to their unique chemical properties,are widely used as catalysts among various catalytic reactions.Abundant Brønsted acid sites in molecular sieve catalysts usually enable ac-tive components to disperse well on the catalyst surface,and help to adsorb a large number of gas molecules to achieve maximum catalytic performance.Therefore,a variety of molecular sieve catalysts have been developed and used in the selective catalytic reduction of NOx by NH3(NH3-SCR).For exam-ple,Cu molecular sieve catalysts such as Cu-SSZ-13 and Cu-SAPO-34 with wide temperature windows and stable structure are considered and applied as commercial catalysts for NOx removal in diesel vehi-cles for a long time.Although molecular sieve catalysts possess many advantages,they still cannot avoid the serious deactivation caused by various factors in practical applications.In this review,reasons lead-ing to the deactivation of molecular sieve catalysts for NOx reduction in actual working conditions were concluded.The deactivation mechanisms of molecular sieve catalysts for NOx reduction were analyzed and the corresponding anti-deactivation strategies were summarized.Finally,challenges and prospects of molecular sieve catalysts for NOx reduction were also proposed.

外文关键词：

Environmental catalysisNOx reductionMolecular sieve catalystsDeactivation mechanismAnti-deactivation

作者：

Fuli Wang、Penglu Wang、Jin Zhang、Dengchao Peng、Mengmeng Wei、Dengsong Zhang

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作者单位：

School of Environmental and Chemical Engineering,State Key Laboratory of Advanced Special Steel,International Joint Laboratory of Catalytic Chemistry,College of Sciences,Shanghai University,Shanghai 200444,China

基金：

国家自然科学基金Chenguang Program supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission

项目编号：

2212560422Z00354

出版年：

2024

DOI：

10.1016/j.cclet.2023.108800

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCD

影响因子：0.771

ISSN：1001-8417

年,卷(期)：2024.35(3)

参考文献量209