Abstract
Small-molecule drugs are widely used in daily life.There are still issues with the current industrial syn-thesis techniques for small-molecule drugs,such as the use of expensive metal catalysts,convoluted reac-tion processes,and non-recyclable catalysts.The benefits of photocatalytic organic synthesis over conven-tional techniques are mild conditions,environmental friendliness,and great selectivity.Porous framework materials can precisely modulate catalytic sites'electronic state and ligand structure to improve photocat-alytic performance.In particular,MOFs,COFs and PCCs based photocatalysts have received extensive re-search interest due to their unique morphology,structural adjustability,high photocatalytic performance,unique recyclability,excellent chemical stability,easy synthesis and low cost.Therefore,a key area for future research is the development of porous framework materials as photocatalysts for the synthesis of small-molecule drugs or drug precursors.
基金项目
国家自然科学基金(21501133)
国家自然科学基金(22371067)
China Hunan Provincial Science and Technology Department(2020RC3020)
China Hunan Provincial Science and Technology Department(2021JJ20021)
NETL
NSTL
万方数据