Abstract
Nitrene transfer reactions are powerful tools in synthetic organic chemistry.In recent years,transition-metal catalyzed nitrene transfer reactions with carbamates as the nitrene precursors have been widely pursued.Such species undergoes facile C-H amination,aziridination,and bifunctionalization of alkenes under the catalysis of different transition metals including Rh,Fe,Ru and others,enabling the efficient construction of various nitrogen-containing molecules.In this review,the recent developments in nitrene transfer reactions with carbamates via N-O bond cleavage were introduced based on different types of reaction,and the key mechanistic information and synthetic applications of the methodologies were dis-cussed.
基金项目
国家自然科学基金(21572163)
国家自然科学基金(21873074)
Wenzhou Science and Technology Bureau(G20210032)
NETL
NSTL
万方数据