Abstract
In 2022,The MOE Key Laboratory of Macromolecular Synthesis and Functionalization in Zhejiang Uni-versity had achieved several important results.First,a series of well-defined dinuclear organoboron cat-alysts were developed to precisely control the enchainment of ether and carbonate segments during the copolymerization of CO2 and epoxides.Second,polyester had been synthesized through cationic copoly-merization of cyclic anhydride.Third,ring-opening polymerization of carbon dioxide based valerolactone had been achieved,revealing the prospect of 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one(EVL)in uti-lizing CO2 and synthesizing functional polymers.Fourth,machine learning methods have been applied to biomaterial research,enabling high-throughput screening of functional biomaterial surfaces for im-plantable devices,and searching for potent antimicrobial peptides in whole combinatorial peptide li-braries.Fifth,methods of characterization of biomacromolecule RNA transcription and manipulation of nucleoside modification were developed.Sixth,artificial enzymes-armed Bifidobacterium Longum probi-otics were established to tune down gut inflammation.Seventh,three-dimensional(3D)printing tech-nologies were used to engineer tough supramolecular hydrogels.Eighth,hydroplastic foaming graphene frameworks for acoustic and conductive polymer composites were provided for application.Ninth,aggre-gate photophysics about the nature of through-space interactions(TSIs)and manipulating their strength in small molecules with non-conjugated structure had been elucidated.Tenth,the forming mechanism of a newfound nested texture in poly(L-lactic acid)(PLLA)spherulitic films had been revealed.Finally,the isotropically dyeing mechanism of KDP single crystals grown from hydrogels have been explored.The related works are reviewed in this paper.
基金项目
SCI-TECH Academy of Zhejiang University()
NETL
NSTL
万方数据