首页|Copper(Ⅰ)-catalyzed interrupted click/radical relay:A four-component modular synthesis of triazole sulfones
Copper(Ⅰ)-catalyzed interrupted click/radical relay:A four-component modular synthesis of triazole sulfones
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A new,four component copper(l)-catalyzed interrupted click/radical relay cascade has been developed.This unprecedented interrupted click reaction provides a rapid modular synthesis of triazole sulfones,important privileged heterocyclic pharmacophores which cannot be accessed by a traditional click reac-tion.Radical interception of cuprate-triazole,the key reaction intermediate formed in situ,is an important feature of this process.
Click reactionTriazoleSulfoneRadical relay
Pengfei Sun、Fang Wei、Chen-Ho Tung、Zhenghu Xu
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Key Lab for Colloid and Interface Chemistry of Education Ministry,Shandong University,Ji'nan 250100,China
Key Laboratory of Organic Chemistry in Jiangxi Province,Institute of Organic Chemistry,Jiangxi Science & Technology Normal University,Nanchang 330013,China
State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China
Functional Molecules of Zhejiang Province,School of Science,Westlake University,Hangzhou 310024,China
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Natural science Foundation of China and Shandong ProvinceNatural science Foundation of China and Shandong ProvinceNatural science Foundation of China and Shandong ProvinceNatural science Foundation of China and Shandong ProvinceFundamental Research Funds of Shandong University
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