首页|Triplet-triplet annihilation upconversion materials as electrophoretic inks
Triplet-triplet annihilation upconversion materials as electrophoretic inks
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Luminescent materials that can be reversibly switched by electric field stimulation are attractive since the potential application for optoelectronic devices.Here we report a triplet-triplet annihilation upconversion(TTA-UC)system with electrophoretic response which is developed as the electrophoretic ink.The TTA-UC system consists of an ionic derivative of 9,10-diphenyl anthracene(DPA)as the annihilator and Pt(ll)octaethylporphyrin(PtOEP)as the sensitizer.Upon applying an electric field,migration and enrichment of positively charged DPA derivatives towards the cathode results in a 20％enhancement of TTA-UC.A quasi-solid film for electrically writing is made using the electrophoretic TTA system as the ink and a platinum electrode as a pen.The prototype of TTA-UC ink demonstrates unique luminescence functions upon electrically writing and erasing,providing a promising strategy to develop electronic devices for display,information storage and encryption.
Qiaoyu Zhang、Guiwen Luo、Jinping Chen、Tianjun Yu、Rui Hu、Guoqiang Yang、Yi Zeng、Yi Li
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Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China
University of Chinese Academy of Sciences,Beijing 100049,China
Key Laboratory of Photochemistry,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China
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