Recent progress and prospects of electrolytes for electrocatalytic nitrogen reduction toward ammonia

Sajid Mahmood ¹Haiyan Wang ²Fang Chen ³Yijun Zhong ²Yong Hu⁴

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作者信息

1. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Department of Chemistry,Zhejiang Normal University,Jinhua 321004,China;The Center for Applied Mathematics and Bioinformatics(CAMB),Gulf University for Science and Technology,Mishref 32093,Kuwait
2. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Department of Chemistry,Zhejiang Normal University,Jinhua 321004,China
3. Hangzhou Institute of Advanced Studies,Zhejiang Normal University,Hangzhou 311231,China
4. Key Laboratory of the Ministry of Education for Advanced Catalysis Materials,Department of Chemistry,Zhejiang Normal University,Jinhua 321004,China;Hangzhou Institute of Advanced Studies,Zhejiang Normal University,Hangzhou 311231,China
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Abstract

Electrochemical nitrogen reduction reaction(ENRR)provides a promising strategy to achieve sustainable synthesis of ammonia.However,despite great efforts devoted to this research field,the problems such as low energy efficiency and weak selectivity still impede its practical implementation.Most of the research to date has been concentrated on creating sophisticated electrocatalysts,and adequate knowledge of elec-trolytes is still lacking.Herein,the recent progress in electrolytes for ENRR,including alkaline,neutral,acidic,water-in-salt,organic,ionic liquid,and mixed water-organic electrolytes,is thoroughly reviewed to obtain an in-depth understanding of their effects on electrocatalytic performance.Recently developed representative electrocatalysts in various types of electrolytes are also introduced,and future research priorities of different electrolytes are proposed to develop new and efficient ENRR systems.

Key words

Electrocatalytic nitrogen reduction/Ammonia/Electrolytes/Production rate/Faradaic efficiency

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基金项目

国家自然科学基金(22272150)

浙江省自然科学基金重大项目(LD22B030002)

浙江省自然科学基金重大项目(LZ23B030002)

Zhejiang Provincial Ten Thousand Talent Program(2021R51009)

Key Science and Technology Project of Jinhua City(2020-1-044)

出版年

2024

中国化学快报(英文版)

中国化学会

中国化学快报(英文版)

CSTPCD

影响因子：0.771

ISSN：1001-8417

参考文献量124

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